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- W1976651610 abstract "Growth of sexithiophene films on both ordered and disordered TiO2(1 1 0) surfaces has been investigated by angle-resolved ultraviolet photoemission spectroscopy, atomic force microscopy, and X-ray diffraction including grazing-incidence characterization. The order (or disorder) of the TiO2(1 1 0)-1 × 1 surface has been observed to profoundly influence the electronic, morphological, and structural properties of the 6T films: the band alignment, which determines the injection efficiency of contacts, has been considerably modified by 0.6 eV, and a morphology with either needle-like or dendritic-like islands has been obtained. The changes in the 6T film properties are associated with the orientational modifications of sexithiophene molecules within the films, either flat-lying or upright standing, 6T(0 1 0) or 6T(1 0 0) crystallites, respectively. The growth of different crystallite orientations is argued to be controlled by the kinetics mediated by the (dis)order of the TiO2(1 1 0) surface rather than exclusively by chemical interaction between the molecule and the substrate." @default.
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- W1976651610 date "2007-01-01" @default.
- W1976651610 modified "2023-10-09" @default.
- W1976651610 title "Sexithiophene films on ordered and disordered TiO2(110) surfaces: Electronic, structural and morphological properties" @default.
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- W1976651610 doi "https://doi.org/10.1016/j.susc.2006.09.020" @default.
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