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- W1976687615 abstract "A new class of amorphous thermoplastic elastomers, potentially important commercially and scientifically, was synthesized from conjugated dienes only by first synthesizing polyisoprene–polybutadiene–polyisoprene (IBI) block copolymers with 1,4-structures with alkyl lithium anionic initiators and subsequently selectively cyclizing polyisoprene blocks with different cationic catalysts. The resulting, essentially gel-free products, consisting of poly(cyclized isoprene-b-butadiene-cyclized isoprene), IcBIc, exhibited heterophase domains of Ic in the polybutdiene matrix. They exhibited stress–strain properties typical of polystyrene–polybutdiene–polystyrene, SBS, thermoplastic elastomers, for instance, Shell Oil Company's Kraton D-1101, but with improved tear strength and superior tensile strength versus temperature profile. This is because the Ic block has higher Tg by about 15°C than displayed by the polystyrene block. The best thermoplastic elastomers were obtained from IBIs containing 35–45 polyisoprene." @default.
- W1976687615 created "2016-06-24" @default.
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- W1976687615 date "1998-11-01" @default.
- W1976687615 modified "2023-09-28" @default.
- W1976687615 title "Novel thermoplastic elastomers via selective modification of conjugated diene block copolymers" @default.
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- W1976687615 doi "https://doi.org/10.1016/s0032-3861(98)00034-2" @default.
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