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- W1976756593 abstract "Reaction of ZnCl2 with R,R-bmbcd (=N,N′-bis(4-methoxy-benzyl)-cyclohexane-1,2-diamine) 1 in ethanol yields the chiral [ZnCl2(R,R-bmbcd)] 2, which crystallizes in the monoclinic space group P21. The Zn atom has a distorted tetrahedral geometry involving two nitrogen atoms of R,R-bmbcd and two chloro ligands with the range of bond lengths, 2.066(2)–2.2289(9) Å. The result of the catalytic enantioselective reduction of acetophenone promoted by R,R-bmbcd:Zn(OTf)2=1:1 mole ratio in the presence of catecholborane for 48 h at 0 °C give (S)-(−)-1-phenylethanol in 48% ee with 77% yield." @default.
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- W1976756593 date "2004-07-01" @default.
- W1976756593 modified "2023-10-14" @default.
- W1976756593 title "Synthesis and characterization of a chiral Zn(II) complex based on a trans-1,2-diaminocyclohexane derivative and catalytic reduction of acetophenone" @default.
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- W1976756593 doi "https://doi.org/10.1016/j.poly.2004.04.033" @default.
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