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• W1976764136 abstract "Abstract This paper reports the synthesis of a polymerizable dppe-derivative with eight pendent styrenyl units linked to the dppe core through four tyrosine residues. This diphosphine ligand was utilized in the synthesis of a series of P2PdX2 complexes (X2=(R)-BINOL, (S)-BINOL, Cl2 and π-1,3-Ph2-allyl+). The compounds were used as comonomers for the synthesis of porous organic polymers (poly EDMA). Molecular imprinting effects on X2-ligand removal were investigated. Overall, the presence of a cavity of significant size was found to be beneficial to the rate of the allylic alkylation reaction, however, chiral BINOL shaped cavities did not influence the enantio-selectivity of the reaction." @default.
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• W1976764136 date "2004-11-01" @default.
• W1976764136 modified "2023-09-23" @default.
• W1976764136 title "Amino-acid containing metallomonomers copolymerized into porous organic polymers: applicability to allylic alkylation catalysis" @default.
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• W1976764136 doi "https://doi.org/10.1016/j.ica.2004.04.017" @default.
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