Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976780945> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1976780945 endingPage "408" @default.
- W1976780945 startingPage "403" @default.
- W1976780945 abstract "Durch oxidativen Ligandenaustausch an Hexahalogenorhenaten(IV) mit BrF3, KBrF4, IF5 und Br2 oder durch Substitutionsreaktionen in organischer Phase sowie durch Festkörperaustauschprozesse werden die folgenden 20 fluorhaltigen Gemischtligandkomplexe von Re(IV) erstmals dargestellt: cis-[ReFBrI4]2−, fac-[ReFBr2I3]2−, mer-[ReFBr3I2]2−, trans-[ReFBr4I]2−, [ReFBr5]2−, trans-[ReFCl4I]2−, trans-[ReFCl4Br]2−, [ReFCl5]2−, cis-[ReF2I4]2−, fac-[ReF2BrI3]2−, all-cis-[ReF2Br2I2]2−, cis-[ReF2BrI2]2−, mer-[ReF2Br3I]2−, cis-[ReF2Br4]2−, cis-[ReF2Cl4]2−, fac-[ReF3I3]2−, fac-[ReF3BrI2]2−, fac-[ReF3Br2I]2−, fac-[ReF3Br3]2− und fac-[ReF3Cl3]2−. Die Isolierung der reinen Komplexe gelingt durch Ionenaustauschchromatographie an DEAE-Cellulose. Sie werden durch stereospezifische Austauschreaktionen in Lösung und durch Elementaranalysen charakterisiert. Preparation of Fluorine Containing Hexahalorhenates(IV) By oxidative ligand exchange on hexahalorhenates(IV) with BrF3, KBrF4, IF5 and Br2 or by substitution reactions in organic solvents as well as by solid state exchange processes 20 fluorine containing mixed ligand complexes are prepared for the first time: cis-[ReFBrI4]2−, fac-[ReFBr2I3]2−, mer-[ReFBr3I2]2−, trans-[ReFBr4I]2−, [ReFBr5]2−, trans-[ReFCl4I]2−, trans-[ReFCl4Br]2−, [ReFCl5]2−, cis-[ReF2I4]2−, fac-[ReF2BrI3]2−, all-cis-[ReF2Br2I2]2−, cis-[ReF2BrI2]2−, mer-[ReF2Br3I]2−, cis-[ReF2Br4]2−, cis-[ReF2Cl4]2−, fac-[ReF3I3]2−, fac-[ReF3BrI2]2−, fac-[ReF3Br2I]2−, fac-[ReF3Br3]2− and fac-[ReF3Cl3]2−. The isolation of the pure complexes has been achieved by ion exchange chromatography on DEAE-cellulose. They are characterized by stereospecific exchange reactions in solution and by elementary analyses." @default.
- W1976780945 created "2016-06-24" @default.
- W1976780945 creator A5016693303 @default.
- W1976780945 creator A5080070499 @default.
- W1976780945 date "1993-02-01" @default.
- W1976780945 modified "2023-10-16" @default.
- W1976780945 title "Darstellung Fluorhaltiger Hexahalogenorhenate(IV)" @default.
- W1976780945 cites W1970957312 @default.
- W1976780945 cites W1974007839 @default.
- W1976780945 cites W1985531681 @default.
- W1976780945 cites W1992453406 @default.
- W1976780945 cites W2004687239 @default.
- W1976780945 cites W2009745901 @default.
- W1976780945 cites W2019166442 @default.
- W1976780945 cites W2035510415 @default.
- W1976780945 cites W2039618664 @default.
- W1976780945 cites W2040964684 @default.
- W1976780945 cites W2065104927 @default.
- W1976780945 cites W2066190042 @default.
- W1976780945 cites W2068877674 @default.
- W1976780945 cites W2070679684 @default.
- W1976780945 cites W2073814559 @default.
- W1976780945 cites W2085855383 @default.
- W1976780945 cites W2085938221 @default.
- W1976780945 cites W2087421467 @default.
- W1976780945 cites W2094896444 @default.
- W1976780945 cites W2114081687 @default.
- W1976780945 cites W2120047190 @default.
- W1976780945 cites W2154198049 @default.
- W1976780945 cites W4231961980 @default.
- W1976780945 cites W4241090237 @default.
- W1976780945 cites W4241131874 @default.
- W1976780945 cites W4247617875 @default.
- W1976780945 cites W4248998418 @default.
- W1976780945 doi "https://doi.org/10.1002/zaac.19936190227" @default.
- W1976780945 hasPublicationYear "1993" @default.
- W1976780945 type Work @default.
- W1976780945 sameAs 1976780945 @default.
- W1976780945 citedByCount "8" @default.
- W1976780945 countsByYear W19767809452015 @default.
- W1976780945 crossrefType "journal-article" @default.
- W1976780945 hasAuthorship W1976780945A5016693303 @default.
- W1976780945 hasAuthorship W1976780945A5080070499 @default.
- W1976780945 hasConcept C116569031 @default.
- W1976780945 hasConcept C155647269 @default.
- W1976780945 hasConcept C161790260 @default.
- W1976780945 hasConcept C170493617 @default.
- W1976780945 hasConcept C176788430 @default.
- W1976780945 hasConcept C178790620 @default.
- W1976780945 hasConcept C185592680 @default.
- W1976780945 hasConcept C187921627 @default.
- W1976780945 hasConcept C55493867 @default.
- W1976780945 hasConcept C71240020 @default.
- W1976780945 hasConceptScore W1976780945C116569031 @default.
- W1976780945 hasConceptScore W1976780945C155647269 @default.
- W1976780945 hasConceptScore W1976780945C161790260 @default.
- W1976780945 hasConceptScore W1976780945C170493617 @default.
- W1976780945 hasConceptScore W1976780945C176788430 @default.
- W1976780945 hasConceptScore W1976780945C178790620 @default.
- W1976780945 hasConceptScore W1976780945C185592680 @default.
- W1976780945 hasConceptScore W1976780945C187921627 @default.
- W1976780945 hasConceptScore W1976780945C55493867 @default.
- W1976780945 hasConceptScore W1976780945C71240020 @default.
- W1976780945 hasIssue "2" @default.
- W1976780945 hasLocation W19767809451 @default.
- W1976780945 hasOpenAccess W1976780945 @default.
- W1976780945 hasPrimaryLocation W19767809451 @default.
- W1976780945 hasRelatedWork W1972580032 @default.
- W1976780945 hasRelatedWork W1978905862 @default.
- W1976780945 hasRelatedWork W1984591603 @default.
- W1976780945 hasRelatedWork W2019674303 @default.
- W1976780945 hasRelatedWork W2052901770 @default.
- W1976780945 hasRelatedWork W2079472980 @default.
- W1976780945 hasRelatedWork W2092499203 @default.
- W1976780945 hasRelatedWork W2134391977 @default.
- W1976780945 hasRelatedWork W2950335410 @default.
- W1976780945 hasRelatedWork W3215616929 @default.
- W1976780945 hasVolume "619" @default.
- W1976780945 isParatext "false" @default.
- W1976780945 isRetracted "false" @default.
- W1976780945 magId "1976780945" @default.
- W1976780945 workType "article" @default.