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- W1976784429 abstract "The average driving force for electromigration acting on ions of each species is calculated for a number of liquid alloys, using a pseudopotential approach due in its present form to Faber. According to the approach, the force acting on an ion is related, within the first Born approximation, to the contribution suitably defined of the ion to the alloy resistivity. The theory generally reproduces the experimental trends. In the case of ${mathrm{Na}}_{x}{mathrm{K}}_{1ensuremath{-}x}$, for which calculations are carried out over the whole range of alloy concentration, the experimentally observed reversal in electromigration direction can be reproduced only at a cost of some loss in accuracy in the resistivity calculation. The numerical results indicate a correlation between effective valence and the effective hard-sphere diameter of an ion: in general, the smaller the solute ion, the more likely it is to migrate towards the anode." @default.
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- W1976784429 date "1976-05-15" @default.
- W1976784429 modified "2023-10-17" @default.
- W1976784429 title "Calculations of the average driving force for electromigration in liquid-metal alloys" @default.
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- W1976784429 doi "https://doi.org/10.1103/physrevb.13.4221" @default.
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