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• W1976809398 startingPage "434" @default.
• W1976809398 abstract "Reactions of cycloaurated gold(III) dichloride complexes, with 1,2-C6H4(NHCOMe)2 and silver(I) oxide, or with C2H4(NHSO2Tol)2 (Tol = p-tolyl) or 1,2-C6H4(NHSO2Tol)2 and trimethylamine, give a series of new auracyclic complexes containing the Au–NR–CH2CH2–NR (R = SO2Tol) and Au–NR–C6H4–NR (R = COMe or SO2Tol) five-membered ring systems. An X-ray structure determination on (2-bp)Au{N(COMe)C6H4N(COMe)} (2-bp = cycloaurated 2-benzylpyridine) shows the presence of puckered metallacyclic rings, with both acetyl substituents positioned below the Au(III) coordination plane. The complex (2-bp)Au{N(COMe)C6H4N(COMe)} undergoes ring cleavage in the presence of halide and water, to give the complex (2-bp)Au{N(COMe)C6H4NH(COMe)}Cl, which was characterised crystallographically, and shown to contain a monodentate amidate ligand. Biological activity studies of the new auracyclic complexes are also reported, against P388 murine leukaemia cells and a range of bacteria and fungi, with a number of complexes showing high activity." @default.
• W1976809398 created "2016-06-24" @default.
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• W1976809398 date "2007-01-01" @default.
• W1976809398 modified "2023-09-25" @default.
• W1976809398 title "Organogold(III) complexes containing chelating bis(amidate) ligands: Synthesis, characterisation and biological activity" @default.
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• W1976809398 doi "https://doi.org/10.1016/j.poly.2006.06.036" @default.
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