FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976836947> ?p ?o ?g. }

• W1976836947 endingPage "6274" @default.
• W1976836947 startingPage "6266" @default.
• W1976836947 abstract "Vibrationally mediated photodissociation is a two-photon technique for studying the spectroscopy and photodissociation dynamics of highly vibrationally excited molecules. In these experiments, a highly vibrationally excited t-butyl hydroperoxide (t-BuOOH) molecule, prepared by excitation in the region of the third overtone of the O–H stretching vibration (4νOH), absorbs a second photon to dissociate to OH and t-butoxy fragments, and laser induced fluorescence determines the quantum state populations of the OH fragment. Vibrational overtone excitation spectra, obtained by varying the vibrational overtone excitation wavelength while monitoring a single OH rotational state, are nearly identical to photoacoustic spectra. We fit the coarse structure in the vibrational overtone excitation spectrum in the region of the 4νOH transition and the photoacoustic spectra in the regions of the 5νOH and 6νOH transitions using a spectroscopic model of the interaction of the O–H bond stretching vibration with the torsional vibration about the O–O bond. This analysis determines the barrier to internal rotation of the O–H and t-butoxy groups through the trans configuration and its variation with vibrational excitation. The trans barrier in the ground vibrational state is 275 cm−1 and increases with vibrational excitation to 425, 575, and 680 cm−1 for t-BuOOH molecules with four, five, and six quanta of O–H stretching excitation, respectively. Comparison of the energy disposal in the vibrationally mediated photodissociation with that for direct photolysis at 376 nm, which adds the same amount of energy to the molecule, illustrates the unique dynamics that can occur when vibrational excitation precedes photodissociation. Single-photon photolysis produces fragments with large recoil velocities, while vibrationally mediated photodissociation produces slowly recoiling fragments having substantially more energy in internal excitation." @default.
• W1976836947 created "2016-06-24" @default.
• W1976836947 creator A5003254841 @default.
• W1976836947 creator A5006159278 @default.
• W1976836947 creator A5081311167 @default.
• W1976836947 date "1989-06-01" @default.
• W1976836947 modified "2023-09-23" @default.
• W1976836947 title "Vibrationally mediated photodissociation of <i>t</i>-butyl hydroperoxide: Vibrational overtone spectroscopy and photodissociation dynamics" @default.
• W1976836947 cites W1499210724 @default.
• W1976836947 cites W1972018194 @default.
• W1976836947 cites W1975796409 @default.
• W1976836947 cites W1976141815 @default.
• W1976836947 cites W1984778877 @default.
• W1976836947 cites W1985848708 @default.
• W1976836947 cites W1986375930 @default.
• W1976836947 cites W1987728816 @default.
• W1976836947 cites W1987890874 @default.
• W1976836947 cites W1988313686 @default.
• W1976836947 cites W1989489335 @default.
• W1976836947 cites W1990442532 @default.
• W1976836947 cites W1993626051 @default.
• W1976836947 cites W2003977172 @default.
• W1976836947 cites W2004886104 @default.
• W1976836947 cites W2010402252 @default.
• W1976836947 cites W2012537222 @default.
• W1976836947 cites W2018801628 @default.
• W1976836947 cites W2023269195 @default.
• W1976836947 cites W2023329811 @default.
• W1976836947 cites W2025858781 @default.
• W1976836947 cites W2027815320 @default.
• W1976836947 cites W2029774903 @default.
• W1976836947 cites W2035024335 @default.
• W1976836947 cites W2036112990 @default.
• W1976836947 cites W2036340238 @default.
• W1976836947 cites W2039523555 @default.
• W1976836947 cites W2041661663 @default.
• W1976836947 cites W2042797665 @default.
• W1976836947 cites W2047313970 @default.
• W1976836947 cites W2055417475 @default.
• W1976836947 cites W2056565841 @default.
• W1976836947 cites W2058162036 @default.
• W1976836947 cites W2077929747 @default.
• W1976836947 cites W2086960942 @default.
• W1976836947 cites W2092674364 @default.
• W1976836947 cites W2095484672 @default.
• W1976836947 cites W2102390372 @default.
• W1976836947 cites W2122786310 @default.
• W1976836947 cites W2122970567 @default.
• W1976836947 cites W2125154025 @default.
• W1976836947 cites W2132429396 @default.
• W1976836947 cites W2159611131 @default.
• W1976836947 cites W2160463509 @default.
• W1976836947 cites W3004725144 @default.
• W1976836947 cites W4241703474 @default.
• W1976836947 doi "https://doi.org/10.1063/1.456343" @default.
• W1976836947 hasPublicationYear "1989" @default.
• W1976836947 type Work @default.
• W1976836947 sameAs 1976836947 @default.
• W1976836947 citedByCount "40" @default.
• W1976836947 countsByYear W19768369472015 @default.
• W1976836947 countsByYear W19768369472016 @default.
• W1976836947 countsByYear W19768369472017 @default.
• W1976836947 countsByYear W19768369472021 @default.
• W1976836947 countsByYear W19768369472022 @default.
• W1976836947 countsByYear W19768369472023 @default.
• W1976836947 crossrefType "journal-article" @default.
• W1976836947 hasAuthorship W1976836947A5003254841 @default.
• W1976836947 hasAuthorship W1976836947A5006159278 @default.
• W1976836947 hasAuthorship W1976836947A5081311167 @default.
• W1976836947 hasConcept C121332964 @default.
• W1976836947 hasConcept C124806180 @default.
• W1976836947 hasConcept C1276947 @default.
• W1976836947 hasConcept C178790620 @default.
• W1976836947 hasConcept C181500209 @default.
• W1976836947 hasConcept C184779094 @default.
• W1976836947 hasConcept C185592680 @default.
• W1976836947 hasConcept C24123453 @default.
• W1976836947 hasConcept C32891209 @default.
• W1976836947 hasConcept C32909587 @default.
• W1976836947 hasConcept C38615331 @default.
• W1976836947 hasConcept C41999313 @default.
• W1976836947 hasConcept C4839761 @default.
• W1976836947 hasConcept C54582936 @default.
• W1976836947 hasConcept C62520636 @default.
• W1976836947 hasConcept C69523127 @default.
• W1976836947 hasConcept C75473681 @default.
• W1976836947 hasConcept C83581075 @default.
• W1976836947 hasConceptScore W1976836947C121332964 @default.
• W1976836947 hasConceptScore W1976836947C124806180 @default.
• W1976836947 hasConceptScore W1976836947C1276947 @default.
• W1976836947 hasConceptScore W1976836947C178790620 @default.
• W1976836947 hasConceptScore W1976836947C181500209 @default.
• W1976836947 hasConceptScore W1976836947C184779094 @default.
• W1976836947 hasConceptScore W1976836947C185592680 @default.
• W1976836947 hasConceptScore W1976836947C24123453 @default.
• W1976836947 hasConceptScore W1976836947C32891209 @default.
• W1976836947 hasConceptScore W1976836947C32909587 @default.
• W1976836947 hasConceptScore W1976836947C38615331 @default.

• next