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- W1976856231 abstract "Co3(HPO4)2(OH)2 has a monoclinic symmetry (space group P21/n), with a = 7.532(1)Å, b = 7.516(1)Å, c = 7.700(2)Å, β = 121.91(1)°, Z = 2. Systematic twinning prevents structural determination from single crystal data. The structure is determined from X-ray powder data by direct methods, the refinements using the Rietveld method (RB = 0.043, RWP = 0.098). The hydrogen atoms are located from neutron powder diffraction data. The material is isostructural with the mineral lazulite. Magnetic properties show a rather complex behavior. A metamagnetic transition is observed at Hc = 0.12T below the long range ordering temperature (TN = 10.6K) The thermal evolution of the magnetic properties above this temperature may be explained by antiferromagnetic coupling between weakly ferromagnetic ordered layers." @default.
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- W1976856231 date "1991-06-01" @default.
- W1976856231 modified "2023-10-17" @default.
- W1976856231 title "Synthesis, crystal structure, and magnetic properties of Co3(HPO4)2(OH)2 related to the mineral lazulite" @default.
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- W1976856231 doi "https://doi.org/10.1016/0022-4596(91)90335-f" @default.
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