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- W1976878134 abstract "Abstract Alcohol effect on decrease in interfacial tension of two-phase dodecane-aqueous NaCl-sodium dodecyl sulphate systems is studied using n-butanol, n-pentanol, and benzyl alcohol. The composition of the mixed, adsorbed, intefacial layer is determined from the Gibbs relationship for various concentrations in surfactant and alcohol. A plot of mean area per molecule and of excess mixing free enthalpy versus alcohol mole fraction in an adsorbed layer showed an extremum, indicating an interaction between the constituents within this layer which is correlated with a strong decrease in interfacial tension with butanol and pentanol. In spite of an important interaction with benzyl alcohol, the interfacial tension is rather high. These different behaviors are discussed in terms of alcohol autoassociation." @default.
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- W1976878134 date "1990-02-01" @default.
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- W1976878134 title "Alcohol effect on interfacial tension in oil—water—sodium dodecyl sulphate systems" @default.
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- W1976878134 doi "https://doi.org/10.1016/0021-9797(90)90142-b" @default.
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