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• W1976890295 abstract "Platinum-195 spectra are reported for [Ptn(CO)2n]2- (n = 3, 6, 9, 12 and 15) and carbon-13 spectra are reported for n = 6, 9 and 12 over a range of temperatures. The spectra provide evidence for (a) intramolecular rotation of the Pt3-triangles about the principal three-fold axis, (b) inter-exchange of Pt3-triangles, (c) lack of terminal/edge carbonyl exchange within the Pt3(CO)3(μ-CO)3 group. Evidence is also presented for the formation of [Ni3Pt3(CO)12]2- on mixing [Pt6(CO)12]2- [Ni6(CO)12]2-." @default.
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• W1976890295 date "1979-11-01" @default.
• W1976890295 modified "2023-10-11" @default.
• W1976890295 title "Stereochemical non-rigidity of a metal polyhedron; carbon-13 and platinum-195 fourier transform nuclear magnetic resonance spectra of [Ptn(CO)2n]2- (n = 3, 6, 9, 12 or 15)" @default.
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• W1976890295 doi "https://doi.org/10.1016/s0022-328x(00)85752-6" @default.
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