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• W1976896571 abstract "New experimental data have been obtained for the methoxy radical by observing at high-resolution laser-induced fluorescence (LIF) and stimulated emission pumping (SEP) transitions between the X̃ E2 and lowest excited à A21 state. The SEP transitions were from the à state (pumped from the X̃ E23/2 spin-orbit component) to the X̃ E21/2 spin-orbit component. These data for the first time directly connect with high precision the spin-orbit components of the X̃ E2 ground state of CH3O. Surprisingly these new SEP observations are inconsistent with predictions of the X̃ state structure based on long-standing analyses primarily based on the microwave spectra of ground state CH3O. It is found that all the experimental data can be understood consistently when the previously accepted value of the spin-orbit coupling constant is adjusted and the reflection parity assignments in the X̃ state are reversed. The latter action changes the sign of a number of reflection-parity-dependent parameters in the X̃ state. The ramifications of the changes and the physical interpretation of the resulting parameters are discussed in some detail." @default.
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• W1976896571 date "2009-02-18" @default.
• W1976896571 modified "2023-10-17" @default.
• W1976896571 title "The spectroscopic characterization of the methoxy radical. I. Rotationally resolved à A21–X̃ E2 electronic spectra of CH3O" @default.
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• W1976896571 doi "https://doi.org/10.1063/1.3072104" @default.
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