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- W1976989208 abstract "Evidence that thio- or oxythiomolybdates may be involved in the inhibitory action of Mo upon Cu metabolism is considered briefly. There are indications that structurally related polymeric derivatives rather than free monomeric (MoOnS4-n)2- species may be involved. Claims that pH adjustment of an aqueous solution of (MoS4)2- yields the polymeric derivatives (Mo2S7)2-, (Mo4S13)2-, or (Mo4S15)6- could not be substantiated. The composition and spectral characteristics of (NMe4) derivatives of products formed within the pH range 4.8–7.3 indicated the persistence of (MoS4)2-. More acid solutions yielded MoS3; traces of (MoOS3)2- formed in 2 M NaOH. Studies of the reaction between (MoS4)2- and Fe(III) salen confirmed the formation of a binuclear complex {(salen)Fe}Mo2S7{Fe(salen)} and indicated that the product retains a strong affinity for Cu. Analogous reactions with (MoOS3)2- or (MoO2S2)2- also yielded binuclear Fe-complexes but which involved only the monomeric Mo-containing species as bridging ligand. Differences in infrared spectra and in the affinity of the products for Cu(II) indicated the preferential formation of thio- rather than oxo-bridged complexes. The physiological implications of these findings are considered." @default.
- W1976989208 created "2016-06-24" @default.
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- W1976989208 date "1982-01-01" @default.
- W1976989208 modified "2023-09-27" @default.
- W1976989208 title "Polymeric ions and polynuclear complexes of thio- and oxythiomolybdates" @default.
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- W1976989208 doi "https://doi.org/10.1016/s0162-0134(00)80084-7" @default.
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