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• W1976989535 abstract "Underpotential deposition of copper on Au(111) is analyzed in the light of first-principles calculations. The existence of a 1 × 1 Cu monolayer on Au(111) at underpotentials can be only understood taking into account the free energy excess delivered by the adsorption of sulfate anions. While a naked copper pseudomorphic monolayer results thermodynamically less stable than bulk copper, accounting for the interaction with sulfate ions delivers an underpotential shift which is comparable with the experimental value." @default.
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• W1976989535 date "2012-11-01" @default.
• W1976989535 modified "2023-10-10" @default.
• W1976989535 title "The underpotential deposition that should not be: Cu(1×1) on Au(111)" @default.
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• W1976989535 doi "https://doi.org/10.1016/j.elecom.2012.09.024" @default.
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