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• W1976994579 abstract "Abstract An ESR line width study of vanadyl acetylacetonate (abbreviated as VO(acac)2) in toluene has been carried out as a function of temperature at 9.5 GHz. It was found that VO(acac)2 was undergoing anisotropic reorientation with N=2.8±1 along a symmetry axis z′=Y, where N is the ratio of R∥/R⊥ and R∥ is the rotational diffusion constant along the molecular Z axis and R⊥ is the rotational diffusion constant perpendicular to the molecular Z axis. The N value obtained was found to be in agreement with N=3.0±1 obtained from the allowed-values equation with ϱx=0.634ϱy−0.910 with ϱx=1 and ϱy=3.0 and is consistent, within experimental error, with N predicted from the Stokes-Einstein model (N=2.1). The results of this study could be useful in simulating ESR spectra of VO(acac)2 in the slow-tumbling region. It can also be used to determine the rotational hydrodynamic radius of the solvated vanadyl complex in neat solution." @default.
• W1976994579 created "2016-06-24" @default.
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• W1976994579 date "1992-11-01" @default.
• W1976994579 modified "2023-09-27" @default.
• W1976994579 title "Determination of the anisotropy of rotational reorientation from ESR line width data" @default.
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• W1976994579 doi "https://doi.org/10.1016/0009-2614(92)80120-z" @default.
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