Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977003870> ?p ?o ?g. }
- W1977003870 endingPage "10110" @default.
- W1977003870 startingPage "10101" @default.
- W1977003870 abstract "Salt-induced phase separation of 1,4-dioxane−water mixtures with NaCl has been investigated from the microscopic to mesoscopic scale by large-angle X-ray scattering (LAXS) and small-angle neutron scattering (SANS) methods. A phase diagram of 1,4-dioxane−water−NaCl mixtures has shown that phase separation takes place in a range of 1,4-dioxane mole fraction, 0.1 < xdio ≤ 0.7. The X-ray radial distribution functions have shown that before phase separation the preferential hydration structures of Na+ and Cl- are enhanced with increasing NaCl concentration and that after phase separation the structures of the organic and aqueous phases are practically similar to those of 1,4-dioxane−water mixtures at the corresponding solvent compositions. The SANS data have been interpreted in terms of the Debye correlation length, LD, as a parameter of concentration fluctuation. The LD values were almost constant at ∼9.4 Å in the range of 0 < xNaCl < ∼0.01, but increased quickly to ∼13 Å at xNaCl = 0.024, which corresponds to 54% of the NaCl concentration required for phase separation. From the present findings, together with the previous results on acetonitrile−water−NaCl mixtures, a possible mechanism for NaCl-induced phase separation of 1,4-dioxane−water mixtures is discussed in terms of hydrogen bonding and dipole−dipole interaction." @default.
- W1977003870 created "2016-06-24" @default.
- W1977003870 creator A5004723673 @default.
- W1977003870 creator A5038325245 @default.
- W1977003870 creator A5058628675 @default.
- W1977003870 creator A5060456082 @default.
- W1977003870 creator A5072099872 @default.
- W1977003870 creator A5074404629 @default.
- W1977003870 creator A5074759762 @default.
- W1977003870 date "2001-09-19" @default.
- W1977003870 modified "2023-10-17" @default.
- W1977003870 title "NaCl-Induced Phase Separation of 1,4-Dioxane−Water Mixtures Studied by Large-Angle X-ray Scattering and Small-Angle Neutron Scattering Techniques" @default.
- W1977003870 cites W1968672116 @default.
- W1977003870 cites W1975439630 @default.
- W1977003870 cites W1976485370 @default.
- W1977003870 cites W1978611010 @default.
- W1977003870 cites W1985428423 @default.
- W1977003870 cites W1991234569 @default.
- W1977003870 cites W1999167255 @default.
- W1977003870 cites W2001255400 @default.
- W1977003870 cites W2007043127 @default.
- W1977003870 cites W2014274663 @default.
- W1977003870 cites W2016260133 @default.
- W1977003870 cites W2025616745 @default.
- W1977003870 cites W2029560333 @default.
- W1977003870 cites W2034053045 @default.
- W1977003870 cites W2037254453 @default.
- W1977003870 cites W2043335851 @default.
- W1977003870 cites W2063990354 @default.
- W1977003870 cites W2068568456 @default.
- W1977003870 cites W2068641532 @default.
- W1977003870 cites W2069968718 @default.
- W1977003870 cites W2070748753 @default.
- W1977003870 cites W2077551887 @default.
- W1977003870 cites W2082800790 @default.
- W1977003870 cites W2094001887 @default.
- W1977003870 cites W2100500294 @default.
- W1977003870 cites W2119148933 @default.
- W1977003870 doi "https://doi.org/10.1021/jp011692w" @default.
- W1977003870 hasPublicationYear "2001" @default.
- W1977003870 type Work @default.
- W1977003870 sameAs 1977003870 @default.
- W1977003870 citedByCount "50" @default.
- W1977003870 countsByYear W19770038702012 @default.
- W1977003870 countsByYear W19770038702013 @default.
- W1977003870 countsByYear W19770038702014 @default.
- W1977003870 countsByYear W19770038702015 @default.
- W1977003870 countsByYear W19770038702016 @default.
- W1977003870 countsByYear W19770038702017 @default.
- W1977003870 countsByYear W19770038702018 @default.
- W1977003870 countsByYear W19770038702019 @default.
- W1977003870 crossrefType "journal-article" @default.
- W1977003870 hasAuthorship W1977003870A5004723673 @default.
- W1977003870 hasAuthorship W1977003870A5038325245 @default.
- W1977003870 hasAuthorship W1977003870A5058628675 @default.
- W1977003870 hasAuthorship W1977003870A5060456082 @default.
- W1977003870 hasAuthorship W1977003870A5072099872 @default.
- W1977003870 hasAuthorship W1977003870A5074404629 @default.
- W1977003870 hasAuthorship W1977003870A5074759762 @default.
- W1977003870 hasConcept C104015590 @default.
- W1977003870 hasConcept C113196181 @default.
- W1977003870 hasConcept C120665830 @default.
- W1977003870 hasConcept C121332964 @default.
- W1977003870 hasConcept C132841051 @default.
- W1977003870 hasConcept C147789679 @default.
- W1977003870 hasConcept C178790620 @default.
- W1977003870 hasConcept C184651966 @default.
- W1977003870 hasConcept C185592680 @default.
- W1977003870 hasConcept C191486275 @default.
- W1977003870 hasConcept C2777463227 @default.
- W1977003870 hasConcept C2780457209 @default.
- W1977003870 hasConcept C36591836 @default.
- W1977003870 hasConcept C43617362 @default.
- W1977003870 hasConcept C44280652 @default.
- W1977003870 hasConceptScore W1977003870C104015590 @default.
- W1977003870 hasConceptScore W1977003870C113196181 @default.
- W1977003870 hasConceptScore W1977003870C120665830 @default.
- W1977003870 hasConceptScore W1977003870C121332964 @default.
- W1977003870 hasConceptScore W1977003870C132841051 @default.
- W1977003870 hasConceptScore W1977003870C147789679 @default.
- W1977003870 hasConceptScore W1977003870C178790620 @default.
- W1977003870 hasConceptScore W1977003870C184651966 @default.
- W1977003870 hasConceptScore W1977003870C185592680 @default.
- W1977003870 hasConceptScore W1977003870C191486275 @default.
- W1977003870 hasConceptScore W1977003870C2777463227 @default.
- W1977003870 hasConceptScore W1977003870C2780457209 @default.
- W1977003870 hasConceptScore W1977003870C36591836 @default.
- W1977003870 hasConceptScore W1977003870C43617362 @default.
- W1977003870 hasConceptScore W1977003870C44280652 @default.
- W1977003870 hasIssue "41" @default.
- W1977003870 hasLocation W19770038701 @default.
- W1977003870 hasOpenAccess W1977003870 @default.
- W1977003870 hasPrimaryLocation W19770038701 @default.
- W1977003870 hasRelatedWork W139908420 @default.
- W1977003870 hasRelatedWork W1513834298 @default.
- W1977003870 hasRelatedWork W1990457359 @default.
- W1977003870 hasRelatedWork W2063639526 @default.
- W1977003870 hasRelatedWork W2092249490 @default.