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- W1977047604 abstract "Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics and mechanism of reduction reactions of embelin have been studied using nanosecond electron pulse radiolysis technique and compared with the oxidation process. Two distinct transients observed in the reduction (λmax = 450 nm) and the oxidation (λmax = 410 nm) processes with various free radicals have been characterized and assigned to two different embelin semiquinone radicals on the basis of pulse radiolysis studies. The structures of these transients have been further ascertained using density functional theory with B3LYP functional and 6-31+G(d,p) basis set. Reduction reaction of embelin has been found to produce delocalized semiquinone anion radical. On the other hand, oxidation of embelin is expected to produce several transient species. However, the calculations suggest that oxidation of hydroquinone group is the first step, which is followed by transformation into carbon-centered radical." @default.
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- W1977047604 date "2009-06-01" @default.
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- W1977047604 title "Formation of semiquinone radical in the reaction of embelin (2,5-dihydroxy-3-undecyl-1,4-benzoquinone) with reductants as well as oxidants. Characterization by pulse radiolysis and structure investigation by quantum chemical study" @default.
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- W1977047604 doi "https://doi.org/10.1016/j.molstruc.2009.03.010" @default.
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