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- W1977072470 abstract "Equilibria of oxygen segregation were established using a solid electrolyte cell Ni/ZrO2(+CaO)/Fe-FeO inside the UHV system. An adsorption isotherm θ = ƒ(po2) was determined by AES which shows two steps. In a first step the p(2×2) structure is formed in the range 10−25<pO2<10−21 bar. In the range 10−21<pO2<10−13 bar the centre sites of that structure are filled. This second step leads to the formation of the c(2×2) structure which is stable in equilibrium with NiO (at pO2 = 1.6×10−13 bar) as was confirmed by studying oxygen segregation in the couple Ni/Ni-NiO. An approximate fit of the data with two additive Langmuir isotherms yields the difference of the enthalpy for occupation of the sites of the p(2×2) structure and of its centre sites which is about 40 kJ / mole oxygen." @default.
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- W1977072470 date "1981-12-01" @default.
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- W1977072470 title "Chemisorption of oxygen on Ni(100) at 850°C under equilibrium conditions" @default.
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- W1977072470 doi "https://doi.org/10.1016/0167-2584(81)90030-x" @default.
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