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- W1977087085 abstract "New supramolecular complexes [(Me 3 Sn)(Ph 3 Sn) 2 Fe(CN) 6 ] (I) and [(n-Bu 3 Sn)(Ph 3 Sn) 2 Fe(CN) 6 ] (II) are readily accessible by straightforward self-assembly of [Fe(CN) 6 ] 3− and hydrated R 3 Sn+/R′ 3 Sn + ions (R = Ph, and R′ = Me or n-Bu). The structural characterization of (I) and (II) is compared with well-documented supramolecular complex containing only Ph 3 Sn + unit, [(Ph 3 Sn) 3 Fe(CN) 6 ]. These novel compounds have wide internal cavities capable of encapsulating voluminous organic compounds, and they behave as host acceptors forming charge transfer complexes (CTC). Thiophene compounds acting as guest donor species are encapsulated within the cavities of the three-dimensional (3D) supramolecular hosts. The structure and physical properties of these hosts and host–guest systems were studied by X-ray powder diffraction, IR, UV/Vis., and magnetic measurements." @default.
- W1977087085 created "2016-06-24" @default.
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- W1977087085 date "2004-12-01" @default.
- W1977087085 modified "2023-10-16" @default.
- W1977087085 title "NOVEL SUPRAMOLECULAR DERIVATIVES CONTAINING TWO R3Sn+ (R = Me, n-Bu, or Ph) CONNECTING UNITS: THE FORMATION OF NOVEL HOST–GUEST SYSTEMS BY THE FACILE ENCAPSULATION OF GUEST THIOPHENE COMPOUNDS" @default.
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- W1977087085 doi "https://doi.org/10.1080/10426500490485336" @default.
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