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- W1977095649 abstract "In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl cations. This fragmentation favours the formation of an ion which, in the electron-deficient carbon-oxygen or carbon-sulphur triple bond, is stabilized by an electron-releasing group. The ring fragmentation was observed to be dependent on the nature of the 3-substituent of the ring when a series of 3-substituted 5,6-dihydro-2-methyl-1,4-oxathiines was investigated." @default.
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- W1977095649 date "1986-09-01" @default.
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- W1977095649 title "Electron impact induced fragmentation of dihydro-1,4-oxathiines. 1. 2,3-substituted 5,6-dihydro-1,4-oxathiines" @default.
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- W1977095649 doi "https://doi.org/10.1002/oms.1210210904" @default.
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