Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977128519> ?p ?o ?g. }
- W1977128519 endingPage "2578" @default.
- W1977128519 startingPage "2573" @default.
- W1977128519 abstract "The interaction between peracetylated β-cyclodextrin and several triphenyl phosphine derivatives was studied in supercritical carbon dioxide (scCO2) by UV−visible spectroscopy. The equilibrium constant for a 1:1 complexation reaction was obtained from titration spectra and calculated using two established mathematical models. The values of the equilibrium constants are 1−3 orders of magnitude smaller than those obtained in aqueous solution with analogous phosphines. This is likely due to the absence in scCO2 of the hydrophobic effect, which is replaced by a corresponding, but weaker, CO2-phobic effect. The largest value of Kf was found for complexes of diphenyl(4-adamantylphenyl)phosphine, which is rationalized on the basis of the excellent fit of the phosphine in the cyclodextrin cavity, leading to enhanced host−guest van der Waals interactions. This study can be considered the first step toward the comprehension of the complexation thermodynamics of modified cyclodextrins soluble in scCO2." @default.
- W1977128519 created "2016-06-24" @default.
- W1977128519 creator A5019364425 @default.
- W1977128519 creator A5031212805 @default.
- W1977128519 creator A5045367455 @default.
- W1977128519 creator A5051563095 @default.
- W1977128519 creator A5064222232 @default.
- W1977128519 creator A5081339327 @default.
- W1977128519 creator A5084261826 @default.
- W1977128519 date "2007-02-17" @default.
- W1977128519 modified "2023-10-14" @default.
- W1977128519 title "Complexation of Phosphine Ligands with Peracetylated β-Cyclodextrin in Supercritical Carbon Dioxide: Spectroscopic Determination of Equilibrium Constants" @default.
- W1977128519 cites W1964354600 @default.
- W1977128519 cites W1967857146 @default.
- W1977128519 cites W1969304444 @default.
- W1977128519 cites W1970032721 @default.
- W1977128519 cites W1978335842 @default.
- W1977128519 cites W1980405524 @default.
- W1977128519 cites W1990237811 @default.
- W1977128519 cites W1995180590 @default.
- W1977128519 cites W1998005513 @default.
- W1977128519 cites W1999726053 @default.
- W1977128519 cites W2004362738 @default.
- W1977128519 cites W2005353981 @default.
- W1977128519 cites W2005371367 @default.
- W1977128519 cites W2007178345 @default.
- W1977128519 cites W2011877753 @default.
- W1977128519 cites W2018075459 @default.
- W1977128519 cites W2030444335 @default.
- W1977128519 cites W2039104539 @default.
- W1977128519 cites W2044387880 @default.
- W1977128519 cites W2045928772 @default.
- W1977128519 cites W2047901602 @default.
- W1977128519 cites W2054172552 @default.
- W1977128519 cites W2077227538 @default.
- W1977128519 cites W2092283282 @default.
- W1977128519 cites W2092993934 @default.
- W1977128519 cites W2093113250 @default.
- W1977128519 cites W2113850659 @default.
- W1977128519 cites W2119273413 @default.
- W1977128519 cites W2131838436 @default.
- W1977128519 cites W2168589896 @default.
- W1977128519 cites W2949848798 @default.
- W1977128519 cites W4238599047 @default.
- W1977128519 doi "https://doi.org/10.1021/jp0673112" @default.
- W1977128519 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17305386" @default.
- W1977128519 hasPublicationYear "2007" @default.
- W1977128519 type Work @default.
- W1977128519 sameAs 1977128519 @default.
- W1977128519 citedByCount "27" @default.
- W1977128519 countsByYear W19771285192012 @default.
- W1977128519 countsByYear W19771285192013 @default.
- W1977128519 countsByYear W19771285192014 @default.
- W1977128519 countsByYear W19771285192016 @default.
- W1977128519 countsByYear W19771285192018 @default.
- W1977128519 countsByYear W19771285192021 @default.
- W1977128519 crossrefType "journal-article" @default.
- W1977128519 hasAuthorship W1977128519A5019364425 @default.
- W1977128519 hasAuthorship W1977128519A5031212805 @default.
- W1977128519 hasAuthorship W1977128519A5045367455 @default.
- W1977128519 hasAuthorship W1977128519A5051563095 @default.
- W1977128519 hasAuthorship W1977128519A5064222232 @default.
- W1977128519 hasAuthorship W1977128519A5081339327 @default.
- W1977128519 hasAuthorship W1977128519A5084261826 @default.
- W1977128519 hasConcept C10710636 @default.
- W1977128519 hasConcept C118419359 @default.
- W1977128519 hasConcept C126061179 @default.
- W1977128519 hasConcept C134458231 @default.
- W1977128519 hasConcept C147597530 @default.
- W1977128519 hasConcept C147789679 @default.
- W1977128519 hasConcept C161790260 @default.
- W1977128519 hasConcept C178790620 @default.
- W1977128519 hasConcept C184866935 @default.
- W1977128519 hasConcept C185592680 @default.
- W1977128519 hasConcept C2777716191 @default.
- W1977128519 hasConcept C2779433975 @default.
- W1977128519 hasConcept C32909587 @default.
- W1977128519 hasConceptScore W1977128519C10710636 @default.
- W1977128519 hasConceptScore W1977128519C118419359 @default.
- W1977128519 hasConceptScore W1977128519C126061179 @default.
- W1977128519 hasConceptScore W1977128519C134458231 @default.
- W1977128519 hasConceptScore W1977128519C147597530 @default.
- W1977128519 hasConceptScore W1977128519C147789679 @default.
- W1977128519 hasConceptScore W1977128519C161790260 @default.
- W1977128519 hasConceptScore W1977128519C178790620 @default.
- W1977128519 hasConceptScore W1977128519C184866935 @default.
- W1977128519 hasConceptScore W1977128519C185592680 @default.
- W1977128519 hasConceptScore W1977128519C2777716191 @default.
- W1977128519 hasConceptScore W1977128519C2779433975 @default.
- W1977128519 hasConceptScore W1977128519C32909587 @default.
- W1977128519 hasIssue "10" @default.
- W1977128519 hasLocation W19771285191 @default.
- W1977128519 hasLocation W19771285192 @default.
- W1977128519 hasOpenAccess W1977128519 @default.
- W1977128519 hasPrimaryLocation W19771285191 @default.
- W1977128519 hasRelatedWork W1977857983 @default.
- W1977128519 hasRelatedWork W2030785988 @default.
- W1977128519 hasRelatedWork W2052397146 @default.