FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977168936> ?p ?o ?g. }

• W1977168936 endingPage "4956" @default.
• W1977168936 startingPage "4947" @default.
• W1977168936 abstract "In situ ultrasonic attenuation spectroscopy is applied to the challenging case of monitoring the nucleation and growth of copper sulfate pentahydrate crystallized from supersaturated aqueous solutions, a system not readily amenable to analysis via optical methods due to the intense blue color of the saturated crystallizing solution. In experiments in the 2.8-L rectilinear reactor of a spectrometer, crystallization and dissolution points are reliably detected from the measured attenuation spectra. There are minor differences between data taken at 10 and 50 MHz, notably the lower frequency data appearing to be more sensitive to the particle formation/dissolution process. The nucleation data reveal that the material crystallizes fairly easily as characterized by a metastable zone width of ca. 3−4 °C and a significantly cooling-rate-dependent nucleation order of reaction of ca. 1.7 reflecting the fact that for high cooling rates the nucleation rate is less than that associated with supersaturation generation. The evolving crystal size distribution following nucleation, calculated from ultrasonic attenuation spectroscopy measurements, reveals well-defined oscillations in the observed crystal sizes consistent with the break-up of crystals larger than ca. 250 μm in this crystallizer. From dynamic measurements of changing particle size and concentration during the crystallization process, apparent crystal mass growth rates are calculated to be between 2.3 × 10-3 kg/m2·s at the maximum cooling rate of 0.55 °C/min and 2.02 × 10-4 kg/m2·s at the minimum cooling rate of 0.2 °C/min. On the basis of these data and assuming a spherical particle model, the linear crystal growth rates are estimated to be between 2.0 × 10-6 m/s at the maximum cooling rate of 0.55 °C/min and 1.8 × 10-7 m/s at the minimum cooling rate of 0.2 °C/min." @default.
• W1977168936 created "2016-06-24" @default.
• W1977168936 creator A5016710636 @default.
• W1977168936 creator A5017732837 @default.
• W1977168936 creator A5034911491 @default.
• W1977168936 creator A5089636051 @default.
• W1977168936 date "2004-07-02" @default.
• W1977168936 modified "2023-10-14" @default.
• W1977168936 title "In Situ Ultrasonic Spectroscopy Study of the Nucleation and Growth of Copper Sulfate Pentahydrate Batch Crystallized from Supersaturated Aqueous Solutions" @default.
• W1977168936 cites W1971982618 @default.
• W1977168936 cites W1978500295 @default.
• W1977168936 cites W1979965384 @default.
• W1977168936 cites W1981712150 @default.
• W1977168936 cites W1993316750 @default.
• W1977168936 cites W2011175104 @default.
• W1977168936 cites W2035423082 @default.
• W1977168936 cites W2075178746 @default.
• W1977168936 cites W2078480319 @default.
• W1977168936 cites W2086489698 @default.
• W1977168936 cites W2089300142 @default.
• W1977168936 cites W2094271680 @default.
• W1977168936 cites W2161735212 @default.
• W1977168936 doi "https://doi.org/10.1021/ie0342560" @default.
• W1977168936 hasPublicationYear "2004" @default.
• W1977168936 type Work @default.
• W1977168936 sameAs 1977168936 @default.
• W1977168936 citedByCount "14" @default.
• W1977168936 countsByYear W19771689362012 @default.
• W1977168936 countsByYear W19771689362013 @default.
• W1977168936 countsByYear W19771689362017 @default.
• W1977168936 countsByYear W19771689362019 @default.
• W1977168936 countsByYear W19771689362022 @default.
• W1977168936 countsByYear W19771689362023 @default.
• W1977168936 crossrefType "journal-article" @default.
• W1977168936 hasAuthorship W1977168936A5016710636 @default.
• W1977168936 hasAuthorship W1977168936A5017732837 @default.
• W1977168936 hasAuthorship W1977168936A5034911491 @default.
• W1977168936 hasAuthorship W1977168936A5089636051 @default.
• W1977168936 hasConcept C107054158 @default.
• W1977168936 hasConcept C113196181 @default.
• W1977168936 hasConcept C121332964 @default.
• W1977168936 hasConcept C147789679 @default.
• W1977168936 hasConcept C153294291 @default.
• W1977168936 hasConcept C178790620 @default.
• W1977168936 hasConcept C184651966 @default.
• W1977168936 hasConcept C185592680 @default.
• W1977168936 hasConcept C187530423 @default.
• W1977168936 hasConcept C192562407 @default.
• W1977168936 hasConcept C199360897 @default.
• W1977168936 hasConcept C200447597 @default.
• W1977168936 hasConcept C203036418 @default.
• W1977168936 hasConcept C26456737 @default.
• W1977168936 hasConcept C2781285689 @default.
• W1977168936 hasConcept C32891209 @default.
• W1977168936 hasConcept C41008148 @default.
• W1977168936 hasConcept C43617362 @default.
• W1977168936 hasConcept C61048295 @default.
• W1977168936 hasConcept C62520636 @default.
• W1977168936 hasConcept C8010536 @default.
• W1977168936 hasConcept C88380143 @default.
• W1977168936 hasConceptScore W1977168936C107054158 @default.
• W1977168936 hasConceptScore W1977168936C113196181 @default.
• W1977168936 hasConceptScore W1977168936C121332964 @default.
• W1977168936 hasConceptScore W1977168936C147789679 @default.
• W1977168936 hasConceptScore W1977168936C153294291 @default.
• W1977168936 hasConceptScore W1977168936C178790620 @default.
• W1977168936 hasConceptScore W1977168936C184651966 @default.
• W1977168936 hasConceptScore W1977168936C185592680 @default.
• W1977168936 hasConceptScore W1977168936C187530423 @default.
• W1977168936 hasConceptScore W1977168936C192562407 @default.
• W1977168936 hasConceptScore W1977168936C199360897 @default.
• W1977168936 hasConceptScore W1977168936C200447597 @default.
• W1977168936 hasConceptScore W1977168936C203036418 @default.
• W1977168936 hasConceptScore W1977168936C26456737 @default.
• W1977168936 hasConceptScore W1977168936C2781285689 @default.
• W1977168936 hasConceptScore W1977168936C32891209 @default.
• W1977168936 hasConceptScore W1977168936C41008148 @default.
• W1977168936 hasConceptScore W1977168936C43617362 @default.
• W1977168936 hasConceptScore W1977168936C61048295 @default.
• W1977168936 hasConceptScore W1977168936C62520636 @default.
• W1977168936 hasConceptScore W1977168936C8010536 @default.
• W1977168936 hasConceptScore W1977168936C88380143 @default.
• W1977168936 hasIssue "16" @default.
• W1977168936 hasLocation W19771689361 @default.
• W1977168936 hasOpenAccess W1977168936 @default.
• W1977168936 hasPrimaryLocation W19771689361 @default.
• W1977168936 hasRelatedWork W115270603 @default.
• W1977168936 hasRelatedWork W1718772896 @default.
• W1977168936 hasRelatedWork W2026498445 @default.
• W1977168936 hasRelatedWork W2038392859 @default.
• W1977168936 hasRelatedWork W2093034317 @default.
• W1977168936 hasRelatedWork W2128536723 @default.
• W1977168936 hasRelatedWork W2337661232 @default.
• W1977168936 hasRelatedWork W3020082495 @default.
• W1977168936 hasRelatedWork W3124431488 @default.
• W1977168936 hasRelatedWork W82787830 @default.
• W1977168936 hasVolume "43" @default.
• W1977168936 isParatext "false" @default.

• next