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• W1977181150 abstract "Illumination of flavin in the presence of N-allythiourea (ATU) inhibits catalytic turnover of flavin between its reduced and oxidized redox states by adduct formation, the adduct being no longer reoxidisable by oxygen. The first step in the mechanism of adduct formation is an electron transfer from ATU to flavin in the photoexcited triplet state. In further steps, the ATU radical cation deprotonates, electronic rearrangement occurs and radical combination with the flavosemiquinone follows, yielding a cyclic product in which ATU is added in the 4a- and 5-position to the flavin chromophore.Reaction rates and yields were determined by flash photolysis and continuous illumination. A photochemical study by variation of the molecular structure of ATU was undertaken to prove the proposed mechanism and to determine the structural requirements of flavin inactivators." @default.
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• W1977181150 date "1984-09-01" @default.
• W1977181150 modified "2023-09-27" @default.
• W1977181150 title "THE REDUCTIVE PHOTOALKYLATION OF FLAVIN BY N-ALLYLTHIOUREA" @default.
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• W1977181150 doi "https://doi.org/10.1111/j.1751-1097.1984.tb04592.x" @default.
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