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• W1977193003 abstract "A highly selective potentiometric sensor for thiocyanate ion based on the use of a newly synthesized organo-palladium ion exchanger complex dispersed in a plasticized poly(vinyl chloride) membrane is described. The sensor displays a Nernstian response (−57.8±0.2 mV decade−1) over a wide linear concentration range of thiocyanate (1.0×10−6–1.0×10−1 mol L−1 ), low detection limit (6.3×10−7 mol L−1), fast response (20 s), stable potential readings (±0.4 mV), good reproducibility (±0.9%), long term stability (8 weeks), high precision (±0.7%) and applicability over a wide pH range (4–10). Negligible interferences are caused by F−, Cl−, I−, Br−, NO3−, NO2−, CN−, SO42−, S2O32−, PO43−, citrate, acetate and oxalate ions. Under hydrodynamic mode of operation (FIA), the calibration slope is −51.1±0.1 mV decade−1, the linear response range is 1.0×10−5–1.0×10−1 mol L−1 SCN− and the sample throughput is 40–45 per hour. The sensor is satisfactory used for manual and flow injection potentiometric determination of SCN− in the saliva and urine of cigarette smokers and non smokers. The data agree fairly well with results obtained by the standard spectrophotometric technique. Direct potentiometry and potentiometric titration of SCN− with Ag+ are also monitored with the sensor." @default.
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• W1977193003 date "2006-11-01" @default.
• W1977193003 modified "2023-09-26" @default.
• W1977193003 title "A Novel Potentiometric Membrane Sensor Based on Aryl Palladium Complex for Selective Determination of Thiocyanate in the Saliva and Urine of Cigarette Smokers" @default.
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• W1977193003 doi "https://doi.org/10.1002/elan.200603640" @default.
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