FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977217354> ?p ?o ?g. }

• W1977217354 endingPage "96" @default.
• W1977217354 startingPage "85" @default.
• W1977217354 abstract "Reactions of Cu2 with several small molecules have been studied in the gas phase, under thermalized conditions at room temperature, in a fast-flow reactor. They fall into one of two categories. Cu2 does not react with O2, N2O, N2, H2, and CH4 at pressures up to 6 torr. This implies bimolecular rate constants of less than 5 × 10−15 cm3 s−1 at 6 torr He. Cu2 reacts with CO, NH3, C2H4, and C3H6 in a manner characteristic of association reactions. Second-order rate constants for all four of these reagents are dependent on total pressure. The reactions with CO, NH3, and C2H4 are in their low pressure limit at up to 6 torr He buffer gas pressure. The reaction with C3H6 begins to show fall-off behavior at pressures above 3 torr. Limiting low-pressure, third-order rate constants are 0.66 ± 0.10, 8.8 ± 1.2, 9.3 ± 1.4, and 85 ± 15 × 10−30 cm6 s−1 in He for CO, NH3, C2H4, and C3H6, respectively. Modeling studies of these rate constants imply that the association complexes are bound by at least 20 kcal mol−1 in the case of C2H4 and C3H6 and at least 25 kcal mol−1 in the other cases. The implications of these results for Cu-ligand bonding are developed in comparison with existing work on the interactions of these ligands with Cu atoms, larger clusters, and surfaces. © 1994 John Wiley & Sons, Inc." @default.
• W1977217354 created "2016-06-24" @default.
• W1977217354 creator A5000323703 @default.
• W1977217354 creator A5044935475 @default.
• W1977217354 creator A5065451116 @default.
• W1977217354 creator A5091544545 @default.
• W1977217354 date "1994-01-01" @default.
• W1977217354 modified "2023-09-27" @default.
• W1977217354 title "Reactions of the copper dimer, Cu2, in the gas phase" @default.
• W1977217354 cites W104401682 @default.
• W1977217354 cites W1828671841 @default.
• W1977217354 cites W1965603563 @default.
• W1977217354 cites W1966624435 @default.
• W1977217354 cites W1968052278 @default.
• W1977217354 cites W1979660540 @default.
• W1977217354 cites W1982641154 @default.
• W1977217354 cites W1984768821 @default.
• W1977217354 cites W1985268540 @default.
• W1977217354 cites W1995197075 @default.
• W1977217354 cites W2004345562 @default.
• W1977217354 cites W2004945157 @default.
• W1977217354 cites W2009387482 @default.
• W1977217354 cites W2030734231 @default.
• W1977217354 cites W2036082801 @default.
• W1977217354 cites W2038032726 @default.
• W1977217354 cites W2045233973 @default.
• W1977217354 cites W2046002177 @default.
• W1977217354 cites W2046328418 @default.
• W1977217354 cites W2058087897 @default.
• W1977217354 cites W2062342199 @default.
• W1977217354 cites W2064007719 @default.
• W1977217354 cites W2075625197 @default.
• W1977217354 cites W2322768881 @default.
• W1977217354 cites W2951100891 @default.
• W1977217354 doi "https://doi.org/10.1002/kin.550260110" @default.
• W1977217354 hasPublicationYear "1994" @default.
• W1977217354 type Work @default.
• W1977217354 sameAs 1977217354 @default.
• W1977217354 citedByCount "11" @default.
• W1977217354 countsByYear W19772173542013 @default.
• W1977217354 crossrefType "journal-article" @default.
• W1977217354 hasAuthorship W1977217354A5000323703 @default.
• W1977217354 hasAuthorship W1977217354A5044935475 @default.
• W1977217354 hasAuthorship W1977217354A5065451116 @default.
• W1977217354 hasAuthorship W1977217354A5091544545 @default.
• W1977217354 hasConcept C113196181 @default.
• W1977217354 hasConcept C121332964 @default.
• W1977217354 hasConcept C127413603 @default.
• W1977217354 hasConcept C135889238 @default.
• W1977217354 hasConcept C147789679 @default.
• W1977217354 hasConcept C148898269 @default.
• W1977217354 hasConcept C178790620 @default.
• W1977217354 hasConcept C185592680 @default.
• W1977217354 hasConcept C188198153 @default.
• W1977217354 hasConcept C2779546866 @default.
• W1977217354 hasConcept C3020013744 @default.
• W1977217354 hasConcept C30646810 @default.
• W1977217354 hasConcept C40875361 @default.
• W1977217354 hasConcept C44280652 @default.
• W1977217354 hasConcept C44740213 @default.
• W1977217354 hasConcept C544778455 @default.
• W1977217354 hasConcept C62520636 @default.
• W1977217354 hasConcept C78519656 @default.
• W1977217354 hasConcept C93391505 @default.
• W1977217354 hasConcept C97355855 @default.
• W1977217354 hasConceptScore W1977217354C113196181 @default.
• W1977217354 hasConceptScore W1977217354C121332964 @default.
• W1977217354 hasConceptScore W1977217354C127413603 @default.
• W1977217354 hasConceptScore W1977217354C135889238 @default.
• W1977217354 hasConceptScore W1977217354C147789679 @default.
• W1977217354 hasConceptScore W1977217354C148898269 @default.
• W1977217354 hasConceptScore W1977217354C178790620 @default.
• W1977217354 hasConceptScore W1977217354C185592680 @default.
• W1977217354 hasConceptScore W1977217354C188198153 @default.
• W1977217354 hasConceptScore W1977217354C2779546866 @default.
• W1977217354 hasConceptScore W1977217354C3020013744 @default.
• W1977217354 hasConceptScore W1977217354C30646810 @default.
• W1977217354 hasConceptScore W1977217354C40875361 @default.
• W1977217354 hasConceptScore W1977217354C44280652 @default.
• W1977217354 hasConceptScore W1977217354C44740213 @default.
• W1977217354 hasConceptScore W1977217354C544778455 @default.
• W1977217354 hasConceptScore W1977217354C62520636 @default.
• W1977217354 hasConceptScore W1977217354C78519656 @default.
• W1977217354 hasConceptScore W1977217354C93391505 @default.
• W1977217354 hasConceptScore W1977217354C97355855 @default.
• W1977217354 hasIssue "1" @default.
• W1977217354 hasLocation W19772173541 @default.
• W1977217354 hasOpenAccess W1977217354 @default.
• W1977217354 hasPrimaryLocation W19772173541 @default.
• W1977217354 hasRelatedWork W1984628657 @default.
• W1977217354 hasRelatedWork W2002732071 @default.
• W1977217354 hasRelatedWork W2006560184 @default.
• W1977217354 hasRelatedWork W2015321541 @default.
• W1977217354 hasRelatedWork W2048358453 @default.
• W1977217354 hasRelatedWork W2071577964 @default.
• W1977217354 hasRelatedWork W2080078138 @default.
• W1977217354 hasRelatedWork W2082234425 @default.
• W1977217354 hasRelatedWork W3197779828 @default.

• next