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- W1977219336 abstract "The solvatochromic comparison method is used to unravel and rationalize solvent effects on the 15N n.m.r. spectra of some N-unsubstituted, N-monoalkyl-, and NN-dialkyl-amides. It is shown that, in addition to solvent polarity–polarizability and type-A hydrogen bonding effects, type-B hydrogen bonding by the second protons of self-associated formamide leads to a significant dependence of the 15N shifts on solvent β values. In the case of the N-monoalkylamides, however, self association is sufficiently strong that the dependence of the shifts on solvent β values is negligible." @default.
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- W1977219336 date "1981-01-01" @default.
- W1977219336 modified "2023-10-09" @default.
- W1977219336 title "Linear solvation energy relationship. Part 11. An analysis of nitrogen-15 solvent shifts in amides" @default.
- W1977219336 doi "https://doi.org/10.1039/p29810000353" @default.
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