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- W1977301167 abstract "An ion-exchange membrane can support transport reaction when the counter-ion of its fixed charges is able to complex a neutral ligand. The coaunter-ion becomes a carreir for the substrate. A model of this process has been developed in which several successive complexes coexist in the membrane, and the relation between the transport and the equilibrium constants has been pointed out. The model is based on two experimental examples: (1) transport of ammonia through the cation-exchange membrane, with Ag+ counter-ion as carrier; (2) transport of boric acid through an anion-exchange membrane with OH− or borate counter-ion as carrier. In the first case, monoammine- and diammine-silver complexes are formed and the substrate is trapped in the complexed form by an extraction process. In the second case, borate and polyborate complex formation formation also allows extraction and, in addition, carrier-mediated transport of boric acid in which free ligand is recovered. This model, which takes into account the equilibrium and transport properties of the membrane shows the important role played in these processes by the stability constants of the complexes formed." @default.
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- W1977301167 date "1988-03-01" @default.
- W1977301167 modified "2023-10-18" @default.
- W1977301167 title "Transport reaction through ion-exchange membranes: modelling of ligand transport by a complexing counter-ion and experiments wih ammine and polyborate ions" @default.
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- W1977301167 doi "https://doi.org/10.1016/0011-9164(88)80050-x" @default.
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