Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977366013> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W1977366013 endingPage "864" @default.
- W1977366013 startingPage "857" @default.
- W1977366013 abstract "The photochemistry of a series of alkyl aryl sulfoxides is described. The initial event of the photolysis process is homolytic cleavage to form sulfinyl/alkyl radical pairs. The radical pair partitions between recombination to starting material, formation of sulfenic esters, disproportionation to an olefin and benzenesulfenic acid, and formation of typical radical escape products. The quantum yield for conversion depends on the structure or the reactivity of the alkyl radical, with the sequence benzyl > tertiary alkyl > secondary alkyl > primary alkyl > (di)aryl. The high racemization efficiency of some aryl primary-alkyl sulfoxides suggests that another nonradical pathway for the photoracemization process may exist. Product analysis does not support any hydrogen abstraction pathways." @default.
- W1977366013 created "2016-06-24" @default.
- W1977366013 creator A5027847955 @default.
- W1977366013 creator A5048972150 @default.
- W1977366013 date "1997-02-01" @default.
- W1977366013 modified "2023-09-27" @default.
- W1977366013 title "Photolysis of Alkyl Aryl Sulfoxides: α-Cleavage, Hydrogen Abstraction, and Racemization<sup>1</sup>" @default.
- W1977366013 cites W1972749047 @default.
- W1977366013 cites W1973609724 @default.
- W1977366013 cites W1985146122 @default.
- W1977366013 cites W1998575940 @default.
- W1977366013 cites W2009381730 @default.
- W1977366013 cites W2015240635 @default.
- W1977366013 cites W2026675311 @default.
- W1977366013 cites W2034770020 @default.
- W1977366013 cites W2040310842 @default.
- W1977366013 cites W2053793461 @default.
- W1977366013 cites W2057682338 @default.
- W1977366013 cites W2061237641 @default.
- W1977366013 cites W2069641664 @default.
- W1977366013 cites W2081139296 @default.
- W1977366013 cites W2088163727 @default.
- W1977366013 cites W2138550717 @default.
- W1977366013 cites W2312972620 @default.
- W1977366013 cites W2315631672 @default.
- W1977366013 cites W2315649202 @default.
- W1977366013 cites W2320276251 @default.
- W1977366013 cites W2329368518 @default.
- W1977366013 cites W2330408076 @default.
- W1977366013 cites W2469460246 @default.
- W1977366013 doi "https://doi.org/10.1021/jo961775m" @default.
- W1977366013 hasPublicationYear "1997" @default.
- W1977366013 type Work @default.
- W1977366013 sameAs 1977366013 @default.
- W1977366013 citedByCount "41" @default.
- W1977366013 countsByYear W19773660132012 @default.
- W1977366013 countsByYear W19773660132013 @default.
- W1977366013 countsByYear W19773660132014 @default.
- W1977366013 countsByYear W19773660132015 @default.
- W1977366013 countsByYear W19773660132016 @default.
- W1977366013 countsByYear W19773660132017 @default.
- W1977366013 countsByYear W19773660132018 @default.
- W1977366013 countsByYear W19773660132020 @default.
- W1977366013 countsByYear W19773660132021 @default.
- W1977366013 countsByYear W19773660132022 @default.
- W1977366013 crossrefType "journal-article" @default.
- W1977366013 hasAuthorship W1977366013A5027847955 @default.
- W1977366013 hasAuthorship W1977366013A5048972150 @default.
- W1977366013 hasConcept C103533665 @default.
- W1977366013 hasConcept C139066938 @default.
- W1977366013 hasConcept C155647269 @default.
- W1977366013 hasConcept C175689099 @default.
- W1977366013 hasConcept C178790620 @default.
- W1977366013 hasConcept C185592680 @default.
- W1977366013 hasConcept C2780263894 @default.
- W1977366013 hasConcept C2781076698 @default.
- W1977366013 hasConcept C54582936 @default.
- W1977366013 hasConcept C60002323 @default.
- W1977366013 hasConcept C75473681 @default.
- W1977366013 hasConcept C81022585 @default.
- W1977366013 hasConceptScore W1977366013C103533665 @default.
- W1977366013 hasConceptScore W1977366013C139066938 @default.
- W1977366013 hasConceptScore W1977366013C155647269 @default.
- W1977366013 hasConceptScore W1977366013C175689099 @default.
- W1977366013 hasConceptScore W1977366013C178790620 @default.
- W1977366013 hasConceptScore W1977366013C185592680 @default.
- W1977366013 hasConceptScore W1977366013C2780263894 @default.
- W1977366013 hasConceptScore W1977366013C2781076698 @default.
- W1977366013 hasConceptScore W1977366013C54582936 @default.
- W1977366013 hasConceptScore W1977366013C60002323 @default.
- W1977366013 hasConceptScore W1977366013C75473681 @default.
- W1977366013 hasConceptScore W1977366013C81022585 @default.
- W1977366013 hasIssue "4" @default.
- W1977366013 hasLocation W19773660131 @default.
- W1977366013 hasOpenAccess W1977366013 @default.
- W1977366013 hasPrimaryLocation W19773660131 @default.
- W1977366013 hasRelatedWork W1977366013 @default.
- W1977366013 hasRelatedWork W2004784739 @default.
- W1977366013 hasRelatedWork W2034893960 @default.
- W1977366013 hasRelatedWork W2078594855 @default.
- W1977366013 hasRelatedWork W2079703770 @default.
- W1977366013 hasRelatedWork W2168926262 @default.
- W1977366013 hasRelatedWork W2324898221 @default.
- W1977366013 hasRelatedWork W2950017750 @default.
- W1977366013 hasRelatedWork W2950354789 @default.
- W1977366013 hasRelatedWork W2952979462 @default.
- W1977366013 hasVolume "62" @default.
- W1977366013 isParatext "false" @default.
- W1977366013 isRetracted "false" @default.
- W1977366013 magId "1977366013" @default.
- W1977366013 workType "article" @default.