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- W1977395222 abstract "Abstract The perfluoro radicals n-C 3 F 7 and iso-C 3 F 7 have been prepared by pyrolyzing the corresponding iodides in a platinum effusion tube at temperatures between 450–550°C and isolated in argon matrices. By eliminating absorption bands attributed to known fluorine compounds and applying relative absorption band intensity correlations, several absorption bands have been assigned, some 30 to n-C 3 F 7 and 29 to iso-C 3 Fe 7 , in the spectral range 2000–200 cm -1 . A tentative vibrational assignment is presented for both species on the assumption of C s symmetry. Some thermodynamic implications of the findings are also discussed." @default.
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- W1977395222 date "1980-07-01" @default.
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- W1977395222 title "Ir matrix isolation spectra of some perfluoro organic free radicals. Part III. n-C3F7 and iso-C3F7" @default.
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- W1977395222 doi "https://doi.org/10.1016/s0022-1139(00)85147-7" @default.
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