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- W1977399233 abstract "Vaporization of the LnCl3–KCl (Ln = Nd and/or Er) equimolar molten mixture was investigated at 1018—1273 K by means of Knudsen effusion mass spectrometry. The vapor species KCl, K2Cl2, NdCl3, and KLnCl4 were found in the vapor over the melt, and their vapor pressures were evaluated for the NdCl3–KCl system. Volatility enhancement of NdCl3 by the formation of the vapor complex KNdCl4 decreases with increase in temperature. A relatively small enthalpy change, −10 ± 21 kJ mol−1, of the isomolecular exchange KNdCl4(g) + KCl(g) = NdCl3(g) + K2Cl2(g) suggests that the structural change of the reaction is not drastic and that the KNdCl4(g) complex has two bridging and two terminal chlorine atoms." @default.
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- W1977399233 date "1996-02-01" @default.
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- W1977399233 title "Mass Spectrometric Investigation of the Vapor over the LnCl<sub>3</sub>–KCl Equimolar Melt (Ln = Nd, Er) at High Temperatures" @default.
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- W1977399233 doi "https://doi.org/10.1246/bcsj.69.353" @default.
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