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- W1977444300 abstract "Abstract A number of high molecular weight polygermanes were prepared by an improvement on Wurtz coupling reactions of dichlorogermanes and sodium metal, and by a method using diiodogermylene and Grignard reagents (or organolithiums). Most of the polygermanes thus prepared showed a narrow molecular distribution containing molecular weights 10 3 –10 4 . In solution, the polygermanes showed characteristic electronic absorption bands at 300–350 nm and were strongly thermochromic for alkyl-substituted derivatives. Photolysis of the polygermanes proceeded by both contraction of the chain with loss of diorganogermylenes and homolytic scission of the germanium—germanium σ bond." @default.
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- W1977444300 date "1994-06-01" @default.
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- W1977444300 title "Synthesis, absorption characteristics and some reactions of polygermanes" @default.
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- W1977444300 doi "https://doi.org/10.1016/0022-328x(94)80104-5" @default.
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