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• W1977483963 abstract "Raman spectroscopic technique was used to study the intermolecular interactions and dynamics of SO stretching vibration of dimethyl sulfoxide (DMSO) molecule using different chemical and isotopic solvents. The Raman bands have been deconvoluted into four distinct bands for neat DMSO and in binary mixtures. Deconvoluted bands in neat DMSO were assigned as monomer, cyclic out-of-phase, cyclic in-phase and chain dimers having peak frequencies 1069.10, 1056.60, 1041.50 and 1027.30 cm− 1 respectively. The vibrational relaxation phenomena of the systems have been studied. Quantum-chemical calculations have been carried out to gain more insight into the self-association of DMSO and its interacting environment with the solvents using the HF/6–31 + G (d, p) method. Theoretical calculations have been compared with the experimental results and we obtained in good agreement of the results." @default.
• W1977483963 created "2016-06-24" @default.
• W1977483963 creator A5042320304 @default.
• W1977483963 creator A5046273025 @default.
• W1977483963 date "2014-09-01" @default.
• W1977483963 modified "2023-10-06" @default.
• W1977483963 title "Raman spectroscopic study of polar aprotic molecule and its molecular associations with chemical and isotopic solvents: Comparative study with quantum-chemical calculations" @default.
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• W1977483963 doi "https://doi.org/10.1016/j.molliq.2014.05.014" @default.
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