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- W1977492790 abstract "Abstract Acceptor numbers ( AN ) of several halogenated and perfluorohalogenated solvents were determined using 31 P NMR of triethylphosphine oxide (Et 3 P O) as a probe. The halogen and/or hydrogen bonding complex, C–X⋯O PEt 3 or C–H⋯O PEt 3 , between the probe and solvent molecules was simulated by MP2 and DFT methods. The halogen bonding energies of perfluorohalogenated solvents and iodobenzene with the probe show a good linear correlation to the AN . The results indicate that the AN can act as a possible criterion for the ability of halogen bonding as a specific solvent effect." @default.
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- W1977492790 date "2013-04-01" @default.
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- W1977492790 title "Acceptor number of halogenated solvents and its potential as a criterion for the ability of halogen bonding as a specific solvent effect using the 31P NMR chemical shift of triethylphosphine oxide as a probe" @default.
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- W1977492790 doi "https://doi.org/10.1016/j.cplett.2013.02.056" @default.
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