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- W1977512748 abstract "Abstract The intrinsic fluorescence of copoly(ester‐imide)s is used to obtain information about the existence of sandwich like arrangement of aromatic units. The copoly(ester‐imide) investigated herein contains tert ‐butylhydroquinone, N ‐(4‐carboxyphenyl)trimellitimide and 2,6‐naphthoate moieties. Depending on the excitation wavelength, different sandwich like arrangements are observed by the change of the fluorescence. Identification of the different interacting units was performed by comparing the copoly(ester‐imide) fluorescence with the fluorescence of different low molecular weight model substances representing different parts of the polymer chain. Ground‐state stable dimer formation between the imide parts and the naphthoate moieties, as well as mixed ground‐state stable complex formation between these parts was observed. All measurements were performed in 1,1,1,3,3,3‐hexafluoro‐2‐propanol (HFIP) solutions. Comparison of copoly(ester‐imide) fluorescence with constituent model substances. magnified image Comparison of copoly(ester‐imide) fluorescence with constituent model substances." @default.
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- W1977512748 date "2003-04-01" @default.
- W1977512748 modified "2023-10-15" @default.
- W1977512748 title "Fluorescence of Copoly(ester‐imide)s Containing 2,6‐Naphthoate Units" @default.
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- W1977512748 doi "https://doi.org/10.1002/macp.200390047" @default.
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