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• W1977535094 startingPage "3622" @default.
• W1977535094 abstract "Abstract The iminophosphorane Ph 2 P(CH 2 Py)(NSiMe 3 ) ( 1 ) was treated with deprotonating alkali metal reagents to give [(Et 2 O)Li{Ph 2 P(CHPy)(NSiMe 3 )}] ( 2 ), [{Ph 2 P(CH 2 Py)(NSiMe 3 )}Li{Ph 2 P(CHPy)(NSiMe 3 )}] ( 3 ) and [{Ph 2 P(CH 2 Py)(NSiMe 3 )}Na{Ph 2 P(CHPy)(NSiMe 3 )}] ( 4 ). We report their coordination behaviour in solid‐state structures and NMR spectroscopic features in solution. Furthermore, we furnish experimental evidence against hypervalency of the phosphorus atom in iminophosphoranes from experimental charge‐density studies and subsequent topological analysis. The topological properties, correlated to the results from NMR spectroscopic investigations, illustrate that the formal PN double bond is better written as a polar P + N − single bond. Additionally, the effects of metal coordination on the bonding parameters of the iminophosphorane and the related anion are discussed." @default.
• W1977535094 created "2016-06-24" @default.
• W1977535094 creator A5003932738 @default.
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• W1977535094 creator A5026369423 @default.
• W1977535094 creator A5047219662 @default.
• W1977535094 date "2004-07-22" @default.
• W1977535094 modified "2023-10-16" @default.
• W1977535094 title "Metal Coordination to the Formal PN Bond of an Iminophosphorane and Charge-Density Evidence against Hypervalent Phosphorus(V)" @default.
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• W1977535094 doi "https://doi.org/10.1002/chem.200400163" @default.
• W1977535094 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15281145" @default.
• W1977535094 hasPublicationYear "2004" @default.
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