Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977548228> ?p ?o ?g. }
- W1977548228 endingPage "2477" @default.
- W1977548228 startingPage "2453" @default.
- W1977548228 abstract "The tables of $l$-dependent ion-core radii ($l=0,1,2$) derived from free-ion quantum defects and previously presented by Simons and Bloch are extended to include halogens and the group-$mathrm{I}ensuremath{-}B$ metals (Cu, Ag, and Au). From these radii hybridized bond-orbital coordinates with $ensuremath{sigma}$ and $ensuremath{pi}$ character are formed. The dual bond-orbital coordinates are used to discuss the structures, uniaxial distortions, and melting points of more than 100 simple binary compounds belonging either to the octet family ${A}^{N}{B}^{Pensuremath{-}N}$ with $P=8$ or to the suboctet family $2ensuremath{le}Pensuremath{le}6$. Two conclusions emerge: the quantum bond-orbital $ensuremath{sigma}$ and $ensuremath{pi}$ dual coordinates describe the physical properties of these materials much more accurately than traditional classical coordinates such as size and electronegativity, and the dual quantum coordinates are equally accurate for octet and suboctet compounds. The success of the quantum coordinates implies that bond charges with $ensuremath{sigma}$ and $ensuremath{pi}$ components make important contributions to the structural energies of these materials. The dual coordinate cellular scheme developed by Miedema and co-workers to describe the sign of the heat of formation of liquid and solid metal alloys is examined within the context of orbital, $l$-dependent ion-core radii. We show that Miedema's original coordinate set is unphysical, but that his inductively revised coordinates which are derived from more than 500 binary phase diagrams are remarkably accurate. Apparent irregularities in the revised coordinates are shown by comparison with the orbital shell model to be correct and the consequence of core shell structure." @default.
- W1977548228 created "2016-06-24" @default.
- W1977548228 creator A5003041175 @default.
- W1977548228 creator A5076118690 @default.
- W1977548228 date "1978-03-15" @default.
- W1977548228 modified "2023-10-14" @default.
- W1977548228 title "Quantum-defect theory of heats of formation and structural transition energies of liquid and solid simple metal alloys and compounds" @default.
- W1977548228 cites W1560312716 @default.
- W1977548228 cites W1967309600 @default.
- W1977548228 cites W1970779786 @default.
- W1977548228 cites W1971104586 @default.
- W1977548228 cites W1971668289 @default.
- W1977548228 cites W1973955035 @default.
- W1977548228 cites W1994056495 @default.
- W1977548228 cites W1999882165 @default.
- W1977548228 cites W2002772706 @default.
- W1977548228 cites W2006204996 @default.
- W1977548228 cites W2008710288 @default.
- W1977548228 cites W2010186808 @default.
- W1977548228 cites W2013024743 @default.
- W1977548228 cites W2017719934 @default.
- W1977548228 cites W2026926665 @default.
- W1977548228 cites W2027759981 @default.
- W1977548228 cites W2031671903 @default.
- W1977548228 cites W2039219601 @default.
- W1977548228 cites W2041961944 @default.
- W1977548228 cites W2043706313 @default.
- W1977548228 cites W2052868905 @default.
- W1977548228 cites W2052956262 @default.
- W1977548228 cites W2061592904 @default.
- W1977548228 cites W2072136994 @default.
- W1977548228 cites W2072708520 @default.
- W1977548228 cites W2084599528 @default.
- W1977548228 cites W2088508178 @default.
- W1977548228 cites W2090891316 @default.
- W1977548228 cites W2092111832 @default.
- W1977548228 cites W2093988253 @default.
- W1977548228 cites W2094170953 @default.
- W1977548228 cites W2094222931 @default.
- W1977548228 cites W2095366359 @default.
- W1977548228 cites W2108580528 @default.
- W1977548228 cites W2123329644 @default.
- W1977548228 cites W2123533841 @default.
- W1977548228 cites W2124704912 @default.
- W1977548228 cites W2131577694 @default.
- W1977548228 cites W2150105757 @default.
- W1977548228 cites W2150597085 @default.
- W1977548228 cites W2164654529 @default.
- W1977548228 cites W2230467557 @default.
- W1977548228 cites W4247883713 @default.
- W1977548228 cites W4254491698 @default.
- W1977548228 doi "https://doi.org/10.1103/physrevb.17.2453" @default.
- W1977548228 hasPublicationYear "1978" @default.
- W1977548228 type Work @default.
- W1977548228 sameAs 1977548228 @default.
- W1977548228 citedByCount "206" @default.
- W1977548228 countsByYear W19775482282012 @default.
- W1977548228 countsByYear W19775482282013 @default.
- W1977548228 countsByYear W19775482282014 @default.
- W1977548228 countsByYear W19775482282015 @default.
- W1977548228 countsByYear W19775482282016 @default.
- W1977548228 countsByYear W19775482282017 @default.
- W1977548228 countsByYear W19775482282018 @default.
- W1977548228 countsByYear W19775482282019 @default.
- W1977548228 countsByYear W19775482282020 @default.
- W1977548228 countsByYear W19775482282021 @default.
- W1977548228 countsByYear W19775482282022 @default.
- W1977548228 countsByYear W19775482282023 @default.
- W1977548228 crossrefType "journal-article" @default.
- W1977548228 hasAuthorship W1977548228A5003041175 @default.
- W1977548228 hasAuthorship W1977548228A5076118690 @default.
- W1977548228 hasConcept C121332964 @default.
- W1977548228 hasConcept C177293861 @default.
- W1977548228 hasConcept C184779094 @default.
- W1977548228 hasConcept C185592680 @default.
- W1977548228 hasConcept C192562407 @default.
- W1977548228 hasConcept C62520636 @default.
- W1977548228 hasConcept C8010536 @default.
- W1977548228 hasConcept C84114770 @default.
- W1977548228 hasConceptScore W1977548228C121332964 @default.
- W1977548228 hasConceptScore W1977548228C177293861 @default.
- W1977548228 hasConceptScore W1977548228C184779094 @default.
- W1977548228 hasConceptScore W1977548228C185592680 @default.
- W1977548228 hasConceptScore W1977548228C192562407 @default.
- W1977548228 hasConceptScore W1977548228C62520636 @default.
- W1977548228 hasConceptScore W1977548228C8010536 @default.
- W1977548228 hasConceptScore W1977548228C84114770 @default.
- W1977548228 hasIssue "6" @default.
- W1977548228 hasLocation W19775482281 @default.
- W1977548228 hasOpenAccess W1977548228 @default.
- W1977548228 hasPrimaryLocation W19775482281 @default.
- W1977548228 hasRelatedWork W1997086491 @default.
- W1977548228 hasRelatedWork W2007936050 @default.
- W1977548228 hasRelatedWork W2067319535 @default.
- W1977548228 hasRelatedWork W2078124205 @default.
- W1977548228 hasRelatedWork W2080067990 @default.
- W1977548228 hasRelatedWork W2089311698 @default.
- W1977548228 hasRelatedWork W2322101219 @default.