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• W1977560983 abstract "The double perovskite Ba2FeMoO6 has been studied by neutron powder diffraction, Mössbauer spectrometry and x-ray absorption spectroscopy, and is compared with Sr2FeMoO6. It is shown that the size of the A-site cation has a large effect upon the nature of the low-temperature state, favouring the majority Fe2+/Mo6+ pair in the case of barium and the Fe3+/Mo5+ pair in the case of strontium. In both cases, an electronic transfer appears as T decreases, interpreted as the existence of a minority t2g ↓ narrow band, where the electron is itinerant." @default.
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• W1977560983 date "2002-11-20" @default.
• W1977560983 modified "2023-10-13" @default.
• W1977560983 title "Electronic distribution in the Ba₂FeMoO₆double perovskite; the A-site size effect" @default.
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• W1977560983 doi "https://doi.org/10.1088/0953-8984/14/47/333" @default.
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