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• W1977588006 abstract "The variation of the optical absorption of carbon nanotubes with their geometry has been a long-standing question at the heart of both metrological and applicative issues, in particular because optical spectroscopy is one of the primary tools for the assessment of the chiral species abundance of samples. Here, we tackle the chirality dependence of the optical absorption with an original method involving ultraefficient energy transfer in porphyrin-nanotube compounds that allows uniform photoexcitation of all chiral species. We measure the absolute absorption cross section of a wide range of semiconducting nanotubes at their ${S}_{22}$ transition and show that it varies by up to a factor of 2.2 with the chiral angle, with type I nanotubes showing a larger absorption. In contrast, the luminescence quantum yield remains almost constant." @default.
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• W1977588006 date "2013-09-26" @default.
• W1977588006 modified "2023-10-14" @default.
• W1977588006 title "Chirality Dependence of the Absorption Cross Section of Carbon Nanotubes" @default.
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• W1977588006 doi "https://doi.org/10.1103/physrevlett.111.137402" @default.
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• W1977588006 hasPublicationYear "2013" @default.
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