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• W1977596140 abstract "The X-ray Cl K absorption spectra in [Co(NH 3 ) 6 ]Cl 3 , [Co(NH 3 ) 5 Cl]Cl 2 , trans-[Co(NH 3 ) 4 Cl 2 ]Cl and Cs 2 [CoCl 4 ] are measured with a high-resolution vacuum two-crystal spectrometer. The spectra, except that of [Co(NH 3 ) 6 ]Cl 3 , show an extremely narrow absorption line at the absorption threshold. The result is interpreted on the basis of molecular orbital theory and it is proposed that the intensity of these narrow absorption lines depends on the chemical state between the cobalt and ligand chlorine ions. The narrow absorption line may well be attributed to transitions of the Cl 1 s electron into the e g * antibonding orbitals having partially the 3 p character of chlorine in [Co(NH 3 ) 5 Cl]Cl 2 and trans-[Co(NH 3 ) 4 Cl 2 ]Cl. In Cs 2 [CoCl 4 ] it may be ascribed to the Cl 1 s - t 2 * transitions." @default.
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• W1977596140 date "1983-03-01" @default.
• W1977596140 modified "2023-10-18" @default.
• W1977596140 title "X-Ray K Absorption Edge Structures of Ligand Chlorine Ion in Some Cobalt Coordination Compounds" @default.
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• W1977596140 doi "https://doi.org/10.1143/jpsj.52.1071" @default.
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