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- W1977598081 abstract "Complex compounds between [211At] astatine(I) and chelating ligands were characterized by electromigration in free electrolytes. O, S and N served as donor atoms in the ligands. Complexes of the type (AtXL) (X− = Cl− and Br−) are formed in ligand exchange reactions, and their stability constants were assessed for X− being Br−. In the case of astatine(I) the stability depends on the kind and number of donor atoms, as well as on substituents at the nitrogen and on the basicity of the ligand. The behaviour of astatine(I) is typical for a strongly polarizable acceptor. The experiments were carried out at 298 K in anhydrous ethanolic solutions at constant ionic strength adjusted to 0.05±0.01 M with Na(H)ClO4." @default.
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- W1977598081 date "1977-01-01" @default.
- W1977598081 modified "2023-10-17" @default.
- W1977598081 title "Stability of some metallic complexes of 1,10-diaza 4,7-dithiadecane" @default.
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- W1977598081 doi "https://doi.org/10.1016/0020-1650(77)80005-6" @default.
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