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• W1977605739 abstract "The new type of ion exchanger and solid acid zirconium sulfonated oligo-polystyrenylphosphonate-phosphate (ZSPSP) supported on ZrO2 (ZSPSP/ZrO2) was prepared and characterized by IR, SEM, TG and DSC. The thermal analysis indicated that the ZSPSP/ZrO2 could be used safely below 200 °C. SEM micrographs demonstrated that ZSPSP/ZrO2 with 1–100 μm of particle diameter was amorphous and microporous structure. Comparing with mineral acids such as H2SO4 and HCl or classical resins such as Amberlyst-15 and Nafion NR50 in the esterification reaction between acetic acid and 1-butanol, the order of catalytic activities was: H2SO4 > HCl > ZSPSP/ZrO2 > Amberlyst-15 > Nafion NR50. ZSPSP/ZrO2 exhibited higher ion exchange capacities and selectivity for Fe3+, Co2+, Ni2+ and Cu2+ ions than for other ions." @default.
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• W1977605739 date "2004-08-01" @default.
• W1977605739 modified "2023-09-22" @default.
• W1977605739 title "Preparation, characterization and application of a new type of ion exchanger and solid acid zirconium sulfonated oligo-polystyrenylphosphonate-phosphate supported on ZrO2" @default.
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• W1977605739 doi "https://doi.org/10.1016/j.molcata.2004.03.003" @default.
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