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- W1977608390 abstract "Abstract Nickel(II), palladium(II), zinc(II) and copper(II) complexes of new constrained 2,2′‐bidipyrrin ligands (H 2 BDP) with a peripheral eight‐membered ring were prepared and examined with respect to coordination modes and conformation. Ni II and Pd II ions form mononuclear complexes with a distorted square‐planar N 4 coordination, which was determined for the palladium derivative by single‐crystal X‐ray diffraction. Zn II ions lead to the formation of dinuclear M 2 L 2 helicates, and for Cu II ions both coordination modes are realized. X‐ray crystallographic analyses reveal short M ··· M distances for the dinuclear helicates of Cu II and Zn II bidipyrrins and individually distinct packing patterns for both in the solid state. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W1977608390 created "2016-06-24" @default.
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- W1977608390 date "2007-04-01" @default.
- W1977608390 modified "2023-10-16" @default.
- W1977608390 title "Helical Transition‐Metal Complexes of Constrained 2,2′‐Bidipyrrins" @default.
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- W1977608390 doi "https://doi.org/10.1002/ejic.200600986" @default.
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