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- W1977679580 abstract "The vibrational properties of adsorbed layers have been studied using inelastic He atom scattering. The substrate was Cu(110) viewed along the [001] and [11̄0] azimuth. The adsorbates included, Kr, Xe, CH4, CD4, C2H6, CO, CO2 and O2 and covered the region of both physisorption and chemisorption. Despite a range of binding energies and mass ratios the vibrational frequencies showed no dependence on the momentum change, i.e. scattering was dispersionless, although intensity changes occurred in the inelastic peaks. There seemed to be no dependence of the adsorbate spectra on coverage below a monolayer. The peaks of CH4 and C2H6 appeared broader than those of Kr and Xe suggesting molecular motions. Further, CH4 and C2H6 gave very similar spectra. Both energy gain and loss events were observed in the inelastic spectrum. For those adsorbates which gave multilayer adsorption (Xe, C2H6) changes in the spectra were observed as the second layer developed. In the latter category also, mixed layers (Xe on C2H6, Xe on CO and C2H6 on Xe) were studied." @default.
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- W1977679580 date "1983-08-01" @default.
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- W1977679580 title "Inelastic atom scattering from layers of atoms and molecules on Cu(110)" @default.
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- W1977679580 doi "https://doi.org/10.1016/0039-6028(83)90363-1" @default.
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