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- W1977682143 abstract "The title compund, [Fe(C5H6N)(C7H7O2)], features one strong intermolecular hydrogen bond of the type N—H⋯O=C [N⋯O = 3.028 (2) Å] between the amine group and the carbonyl group of a neighbouring molecule, and vice versa, to form a centrosymmetric dimer. Furthermore, the carbonyl group acts as a double H-atom acceptor in the formation of a second, weaker, hydrogen bond of the type C—H⋯O=C [C⋯O = 3.283 (2) Å] with the methyl group of the ester group of a second neighbouring molecule at (x, −y − {1over 2}, z − {1over 2}). The methyl group also acts as a weak hydrogen-bond donor, symmetry-related to the latter described C—H⋯O=C interaction, to a third molecule at (x, −y − {1over 2}, z + {1over 2}) to form a two-dimensional network. The cyclopentadienyl rings of the ferrocene unit are parallel to each other within 0.33 (3)° and show an almost eclipsed 1,1′-conformation, with a relative twist angle of 9.32 (12)°. The ester group is twisted slightly [11.33 (8)°] relative to the cylopentadienyl plane due to the above-mentioned intermolecular hydrogen bonds of the carbonyl group. The N atom shows pyramidal coordination geometry, with the sum of the X—N—Y angles being 340 (3)°." @default.
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- W1977682143 date "2010-08-18" @default.
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- W1977682143 title "Ferrocene compounds: methyl 1′-aminoferrocene-1-carboxylate" @default.
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- W1977682143 doi "https://doi.org/10.1107/s0108270110025746" @default.
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