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- W1977704294 abstract "The crystal structure of BaTi 2 O 5 in metastable β-state synthesized by the containerless method is derived at the charge density levels by analyzing high-energy synchrotron-radiation powder-diffraction data. The characteristic features are revealed in terms of chemical bonding of the two types of Ti–O polyhedra with fivefold oxygen coordination: a trigonal-bipyramid-type Ti–O 5 and a square-pyramid-type Ti–O 5 . We consider that the structures of metastable states observed in BaTi 2 O 5 , including the glass, are distinguished by the formation of the Ti–O 5 trigonal bipyramid." @default.
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- W1977704294 date "2010-09-01" @default.
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- W1977704294 title "Charge Density Study of Metastable State in BaTi<sub>2</sub>O<sub>5</sub> with Fivefold Coordinated Ti" @default.
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- W1977704294 doi "https://doi.org/10.1143/jjap.49.09me10" @default.
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