Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977738978> ?p ?o ?g. }
- W1977738978 endingPage "3250" @default.
- W1977738978 startingPage "3242" @default.
- W1977738978 abstract "Abstract Thiyl radical mediated reversible H abstraction from the stereogenic center α to the nitrogen atom is a mild method to racemize benzylic amines. Owing to the sensitivity of atom‐transfer reactions to enthalpic effects, a knowledge of both the S–H and the α‐C–H bond dissociation energies is fundamental to select the thiol that is appropriate to abstract the hydrogen atom from a given amine. In the absence of experimental data, theoretical calculations supply a useful predictive tool. The experiments described here are helpful in delineating the optimal conditions that have to be fulfilled for the racemization to proceed in a reasonable time in the presence of either a stoichiometric or a catalytic amount of thiol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
- W1977738978 created "2016-06-24" @default.
- W1977738978 creator A5034171951 @default.
- W1977738978 creator A5050219358 @default.
- W1977738978 creator A5051147414 @default.
- W1977738978 creator A5058449706 @default.
- W1977738978 creator A5062898260 @default.
- W1977738978 creator A5076740332 @default.
- W1977738978 date "2006-06-26" @default.
- W1977738978 modified "2023-10-06" @default.
- W1977738978 title "Thiyl Radical Mediated Racemization of Benzylic Amines" @default.
- W1977738978 cites W1972594727 @default.
- W1977738978 cites W1981616362 @default.
- W1977738978 cites W1985569083 @default.
- W1977738978 cites W1988946181 @default.
- W1977738978 cites W1995000974 @default.
- W1977738978 cites W1995402495 @default.
- W1977738978 cites W1997400894 @default.
- W1977738978 cites W2000937707 @default.
- W1977738978 cites W2009925624 @default.
- W1977738978 cites W2014326399 @default.
- W1977738978 cites W2015543188 @default.
- W1977738978 cites W2015937918 @default.
- W1977738978 cites W2016594355 @default.
- W1977738978 cites W2017905772 @default.
- W1977738978 cites W2019279795 @default.
- W1977738978 cites W2029300374 @default.
- W1977738978 cites W2032069656 @default.
- W1977738978 cites W2034478273 @default.
- W1977738978 cites W2038767330 @default.
- W1977738978 cites W2041115376 @default.
- W1977738978 cites W2051118616 @default.
- W1977738978 cites W2051419557 @default.
- W1977738978 cites W2058611945 @default.
- W1977738978 cites W2058676923 @default.
- W1977738978 cites W2059868408 @default.
- W1977738978 cites W2060390014 @default.
- W1977738978 cites W2068881058 @default.
- W1977738978 cites W2071982166 @default.
- W1977738978 cites W2075730114 @default.
- W1977738978 cites W2079429541 @default.
- W1977738978 cites W2082884975 @default.
- W1977738978 cites W2083689976 @default.
- W1977738978 cites W2094903353 @default.
- W1977738978 cites W2107708637 @default.
- W1977738978 cites W2111412919 @default.
- W1977738978 cites W2128282797 @default.
- W1977738978 cites W2151478644 @default.
- W1977738978 cites W2166345527 @default.
- W1977738978 cites W2180676564 @default.
- W1977738978 cites W2201262498 @default.
- W1977738978 cites W2950269691 @default.
- W1977738978 cites W3004442729 @default.
- W1977738978 cites W2024124458 @default.
- W1977738978 cites W2136273196 @default.
- W1977738978 doi "https://doi.org/10.1002/ejoc.200600120" @default.
- W1977738978 hasPublicationYear "2006" @default.
- W1977738978 type Work @default.
- W1977738978 sameAs 1977738978 @default.
- W1977738978 citedByCount "38" @default.
- W1977738978 countsByYear W19777389782012 @default.
- W1977738978 countsByYear W19777389782013 @default.
- W1977738978 countsByYear W19777389782014 @default.
- W1977738978 countsByYear W19777389782015 @default.
- W1977738978 countsByYear W19777389782016 @default.
- W1977738978 countsByYear W19777389782018 @default.
- W1977738978 countsByYear W19777389782020 @default.
- W1977738978 countsByYear W19777389782021 @default.
- W1977738978 countsByYear W19777389782022 @default.
- W1977738978 countsByYear W19777389782023 @default.
- W1977738978 crossrefType "journal-article" @default.
- W1977738978 hasAuthorship W1977738978A5034171951 @default.
- W1977738978 hasAuthorship W1977738978A5050219358 @default.
- W1977738978 hasAuthorship W1977738978A5051147414 @default.
- W1977738978 hasAuthorship W1977738978A5058449706 @default.
- W1977738978 hasAuthorship W1977738978A5062898260 @default.
- W1977738978 hasAuthorship W1977738978A5076740332 @default.
- W1977738978 hasConcept C102931765 @default.
- W1977738978 hasConcept C131779359 @default.
- W1977738978 hasConcept C134195300 @default.
- W1977738978 hasConcept C139066938 @default.
- W1977738978 hasConcept C146686406 @default.
- W1977738978 hasConcept C147597530 @default.
- W1977738978 hasConcept C155647269 @default.
- W1977738978 hasConcept C161790260 @default.
- W1977738978 hasConcept C178790620 @default.
- W1977738978 hasConcept C185592680 @default.
- W1977738978 hasConcept C2776640939 @default.
- W1977738978 hasConcept C2780263894 @default.
- W1977738978 hasConcept C2781324293 @default.
- W1977738978 hasConcept C60002323 @default.
- W1977738978 hasConcept C81022585 @default.
- W1977738978 hasConceptScore W1977738978C102931765 @default.
- W1977738978 hasConceptScore W1977738978C131779359 @default.
- W1977738978 hasConceptScore W1977738978C134195300 @default.
- W1977738978 hasConceptScore W1977738978C139066938 @default.
- W1977738978 hasConceptScore W1977738978C146686406 @default.
- W1977738978 hasConceptScore W1977738978C147597530 @default.