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- W1977764355 abstract "The simple 1:1 reaction of naphthalene-2,3-diol (H2Np) with Ti(OiPr)4 has a complicated outcome, one rich in diversity and elucidated in this paper by X-ray crystallography and NMR spectroscopy. The reaction in CDCl3 produces a crystalline precipitate, which was found to be the symmetrical dimer [TiNp(OiPr)2]2(HOiPr)2 whose coordinated HOiPr units are hydrogen bonded to OiPr groups (A). A second crystal was also harvested and found to be a partially hydrolyzed 6:6 assembly [Ti3(μ3-O)(μ-Np)2(Np)(μ-OiPr)(OiPr)(HOiPr)2(μ-O)]2 (B) constructed of μ-oxo-linked inverted halves, each a 3:3 assembly anchored by a μ3-oxo group. The supernatant was deduced to contain a soluble 3:3 product [TiNp(OiPr)2]3(HOiPr) possessing the same stereochemistry as B and its likely hydrolysis precursor. When A was redissolved, it produced what appeared to be a 4:4 condensation product, which was also present in the supernatant when the reaction was conducted in the presence of HOiPr-absorbing 13X molecular sieves, or when the reaction mixture was heated. In an analogous reaction, Ti(OtBu)4 produced only an A-like dimeric product possessing pentacoordinate metal centers." @default.
- W1977764355 created "2016-06-24" @default.
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- W1977764355 date "2007-09-29" @default.
- W1977764355 modified "2023-10-07" @default.
- W1977764355 title "Structurally Diverse Aggregating Condensations of Ti(IV) Catecholates" @default.
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- W1977764355 doi "https://doi.org/10.1021/ic7013495" @default.
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