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- W1977772904 abstract "Sediments from a shallow, restricted estuary in southeast Australia were analysed for Ti, V, Cr, Mn, Fe, Co, Cu, Ni, Zn, P2O5 and organic carbon. Subjective interpretation of factor analysis on a geochemical basis, indicates that the dominant controls on the distribution and concentration of these metals and P2O5 in the mud sediments are the mineralogy of land-derived detritus and the chemical conditions of the environment in which the sediments are deposited. None of the transition-metal contents of the sediments, apart from Cr and possibly Cu, can be directly attributed to enrichment over that due to areal variation in detrital mineralogy. Chromium may be precipitated from the water column as a hydroxide in reducing environments, and Cu may be supplied to some extent by organic matter. Phosphate is enriched in the sediment through its association with organic matter. Manganese concentrations are depleted from the surface sediments of reducing environments. Iron sulphide and associated Ni and Zn sulphides are probably formed largely through early diagenetic reactions involving the mobilization of these metals from detrital mineral phases into authigenic phases. Evidence for the presence of these authigenic phases is found in sediments from areas where reducing conditions are likely to be most prevalent." @default.
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- W1977772904 date "1975-11-01" @default.
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- W1977772904 title "Geochemistry of muds from a shallow restricted estuary, Australia" @default.
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- W1977772904 doi "https://doi.org/10.1016/0025-3227(75)90082-1" @default.
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