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- W1977789712 abstract "The hydrolytic reactions of cadmium(II) ions were studied at 25 °C in dioxane–water and methanol–water mixtures with varying compositions of the organic solvents, each mixture containing 3 mol dm−3 (Li)ClO4 as an ionic medium. Emf measurements were carried out over the range of the total cadmium(II) concentrations of 0.2 to 0.8 mol dm−3 in all the systems. Two complexes Cd2OH3+ and CdOH+ were found in the dioxane–water mixtures, but the latter complex was not detected in the methanol–water system. The formation constant of the Cd2OH3+ complex was slightly larger in the methanol–water mixtures than in the dioxane–water mixtures at the same mole-fraction concentration of the organic solvents." @default.
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- W1977789712 date "1977-06-01" @default.
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- W1977789712 title "Ionic Equilibria in Mixed Solvents. XII. Hydrolysis of Cadmium(II) Ion in Dioxane–Water and Methanol–Water Mixtures" @default.
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- W1977789712 doi "https://doi.org/10.1246/bcsj.50.1472" @default.
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