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• W1977795422 abstract "The nonisothermal crystallization half-time (t0.5), defined as the time taken for a polymer film to reach half of its equilibrium crystallinity, was estimated from Raman spectroscopic measurements of crystallinity during blown film extrusion of a linear low-density polyethylene (LLDPE) and an isotactic polypropylene (i-PP). The crystalline a- and c-axis orientation of LLDPE and i-PP films, respectively, increased with decreasing crystallization half-time. The transverse direction tensile modulus and tear strengths for LLDPE films also increased with decreasing half-time. However, for i-PP films, only the transverse direction tear strength increased with decreasing t0.5, while the machine direction properties did not show a significant dependence on half-time. Our real-time Raman spectroscopy studies provide experimental evidence to theories proposed in the literature1-3 with regards to the influence of the nonisothermal crystallization process (along the film axis) on the imparted final film structure. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1740–1747, 2005" @default.
• W1977795422 created "2016-06-24" @default.
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• W1977795422 date "2005-01-01" @default.
• W1977795422 modified "2023-10-16" @default.
• W1977795422 title "Real-time Raman spectroscopic measurement of crystallization kinetics and its effect on the morphology and properties of polyolefin blown films" @default.
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• W1977795422 doi "https://doi.org/10.1002/app.22357" @default.
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